Copa Libertadores 2024, Group E |
 | 28.05.2024 | | Bolívar | – | Palestino | | |
| La Paz |
Copa Libertadores 2024, Group E |
| 08.05.2024 | | Millonarios | – | Bolívar | | 1:1 (1:0) |
| Bogotá |
Copa Libertadores 2022, Second round |
| 23.02.2022 | | Bolívar | – | Universidad Católica | | 1:1 (1:1) |
| La Paz |
Copa Libertadores 2020, Group B |
| 22.09.2020 | | Tigre | – | Bolívar | | 1:1 (1:1) |
| Victoria |
Copa Libertadores 2018, Group 2 |
| 14.03.2018 | | Bolívar | – | Colo-Colo | | 1:1 (1:1) |
| La Paz |
Copa Libertadores 2018, Group 2 |
| 28.02.2018 | | Delfín | – | Bolívar | | 1:1 (1:1) |
| Manta |
Copa Libertadores 2016, Group 3 |
| 20.04.2016 | | Bolívar | – | Racing Club | | 1:1 (0:0) |
| La Paz |
Copa Libertadores 2016, Group 3 |
| 14.04.2016 | | Deportivo Cali | – | Bolívar | | 1:1 (1:0) |
| Santiago de Cali |
Copa Libertadores 2016, Group 3 |
| 10.03.2016 | | Bolívar | – | Boca Juniors | | 1:1 (1:0) |
| La Paz |
Copa Libertadores 2014, Quarterfinal |
| 08.05.2014 | | Lanús | – | Bolívar | | 1:1 (1:0) |
| Lanús |
Copa Libertadores 2014, Round of 16 |
| 22.04.2014 | | Bolívar | – | León | | 1:1 (1:1) |
| La Paz |
Copa Libertadores 2014, Round of 16 |
| 16.04.2014 | | León | – | Bolívar | | 2:2 (1:1) |
| León |
Copa Libertadores 2014, Group 7 |
| 12.03.2014 | | Flamengo | – | Bolívar | | 2:2 (0:0) |
| Rio de Janeiro |
Copa Libertadores 2014, Group 7 |
| 19.02.2014 | | Bolívar | – | León | | 1:1 (0:1) |
| La Paz |
Copa Libertadores 2012, Group 3 |
| 09.02.2012 | | Universidad Católica | – | Bolívar | | 1:1 (1:1) |
| Santiago |
Copa Libertadores 2011, Preliminary Round |
| 03.02.2011 | | Unión Española | – | Bolívar | | 0:0 |
| Santiago |
Copa Libertadores 2010, Group 3 |
| 09.03.2010 | | Bolívar | – | Estudiantes La Plata | | 0:0 |
| La Paz |
Copa Libertadores 2007, Group 7 |
| 14.02.2007 | | Bolívar | – | Boca Juniors | | 0:0 |
| La Paz |
Copa Libertadores 2006, Group 2 |
| 15.02.2006 | | Santa Fe | – | Bolívar | | 2:2 (1:0) |
| Bogotá |
Copa Libertadores 2005, Group 2 |
| 27.04.2005 | | Bolívar | – | LDU | | 2:2 (2:0) |
| La Paz |
Copa Libertadores 2002, Group 4 |
| 12.03.2002 | | Bolívar | – | Atlético-PR | | 5:5 (1:5) |
| La Paz |
Copa Libertadores 2002, Group 4 |
| 20.02.2002 | | Bolívar | – | América de Cali | | 1:1 (0:1) |
| La Paz |
Copa Libertadores 2000, Group 8 |
| 14.03.2000 | | Cobreloa | – | Bolívar | | 3:3 (3:0) |
| Calama |
Copa Libertadores 1998, Quarterfinal |
| 13.05.1998 | | Bolívar | – | Barcelona | | 1:1 (0:0) |
| La Paz |
Copa Libertadores 1998, Group 4 |
| 18.03.1998 | | Oriente Petrolero | – | Bolívar | | 1:1 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1997, 1/8 finals |
| 23.04.1997 | | Minervén | – | Bolívar | | 1:1 (0:0) |
| Puerto Ordaz |
Copa Libertadores 1997, Group 1 |
| 12.03.1997 | | Bolívar | – | Oriente Petrolero | | 3:3 (1:2) |
| La Paz |
Copa Libertadores 1995, Group 5 |
| 21.03.1995 | | Alianza Lima | – | Bolívar | | 1:1 (1:0) |
| Lima |
Copa Libertadores 1995, Group 5 |
| 08.03.1995 | | Jorge Wilstermann | – | Bolívar | | 1:1 (1:0) |
| Cochabamba |
Copa Libertadores 1995, Group 5 |
| 24.02.1995 | | Bolívar | – | Sporting Cristal | | 1:1 (0:1) |
| La Paz |
Copa Libertadores 1994, Group 5 |
| 16.03.1994 | | The Strongest | – | Bolívar | | 0:0 |
| La Paz |
Copa Libertadores 1994, Group 5 |
| 01.03.1994 | | Minervén | – | Bolívar | | 1:1 (1:0) |
| Puerto Ordaz |
Copa Libertadores 1994, Group 5 |
| 23.02.1994 | | Bolívar | – | The Strongest | | 0:0 |
| La Paz |
Copa Libertadores 1993, 1/8 finals |
| 14.04.1993 | | Bolívar | – | América de Cali | | 1:1 (1:0) |
| La Paz |
Copa Libertadores 1993, Group 2 |
| 30.03.1993 | | Cobreloa | – | Bolívar | | 1:1 (0:0) |
| Calama |
Copa Libertadores 1992, Group 2 |
| 27.03.1992 | | Bolívar | – | Criciúma | | 1:1 (0:0) |
| La Paz |
Copa Libertadores 1992, Group 2 |
| 20.03.1992 | | Bolívar | – | São Paulo | | 1:1 (1:0) |
| La Paz |
Copa Libertadores 1991, 1/8 finals |
| 24.04.1991 | | Bolívar | – | Nacional Montevideo | | 1:1 (0:1) |
| La Paz |
Copa Libertadores 1991, Group 1 |
| 29.03.1991 | | Boca Juniors | – | Bolívar | | 0:0 |
| Buenos Aires |
Copa Libertadores 1989, Group 5 |
| 08.03.1989 | | The Strongest | – | Bolívar | | 0:0 |
| La Paz |
Copa Libertadores 1989, Group 5 |
| 17.02.1989 | | Bolívar | – | The Strongest | | 0:0 |
| La Paz |
Copa Libertadores 1986, Semifinal group 2 |
| 30.09.1986 | | Bolívar | – | Olimpia | | 1:1 (0:0) |
| La Paz |
Copa Libertadores 1986, First Round, Group 3 |
| 24.05.1986 | | Universidad Técnica | – | Bolívar | | 2:2 (2:1) |
| Cajamarca |
Copa Libertadores 1984, First Round, Group 2 |
| 09.05.1984 | | O'Higgins | – | Bolívar | | 0:0 |
| Rancagua |
Copa Libertadores 1984, First Round, Group 2 |
| 17.03.1984 | | Bolívar | – | Blooming | | 0:0 |
| La Paz |
Copa Libertadores 1979, First Round, Group 2 |
| 15.04.1979 | | Sol de América | – | Bolívar | | 2:2 (1:1) |
| Asunción |
Copa Libertadores 1977, First Round, Group 2 |
| 15.05.1977 | | Oriente Petrolero | – | Bolívar | | 0:0 |
| Santa Cruz de la Sierra |
Copa Libertadores 1970, First Round, Group 1 |
| 05.03.1970 | | Bolívar | – | River Plate | | 1:1 (0:0) |
| La Paz |
Copa Libertadores 1970, First Round, Group 1 |
| 15.02.1970 | | Universitario La Paz | – | Bolívar | | 2:2 (1:1) |
| La Paz |
Copa Libertadores 1969, First Round, Group 3 |
| 02.03.1969 | | Cerro Porteño | – | Bolívar | | 1:1 (0:1) |
| Asunción |
Copa Libertadores 1969, First Round, Group 3 |
| 22.02.1969 | | Litoral | – | Bolívar | | 1:1 (1:1) |
| Cochabamba |
Copa Libertadores 1969, First Round, Group 3 |
| 13.02.1969 | | Bolívar | – | Olimpia | | 1:1 (0:1) |
| La Paz |
Copa Libertadores 1967, First Round, Group 2 |
| 14.05.1967 | | 31 de Octubre | – | Bolívar | | 2:2 (1:1) |
| La Paz |
Copa Libertadores 1967, First Round, Group 2 |
| 28.04.1967 | | Bolívar | – | Santa Fe | | 2:2 (1:1) |
| La Paz |
Copa Libertadores 1967, First Round, Group 2 |
| 23.04.1967 | | Bolívar | – | Independiente Medellín | | 1:1 (0:0) |
| Argentina, La Paz |
Copa Libertadores 1967, First Round, Group 2 |
| 19.03.1967 | | Bolívar | – | River Plate | | 3:3 (1:1) |
| La Paz |
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