Copa Libertadores 2001, Preliminary Round |
| 31.10.2000 | | Atlante | | Deportivo Italchacao | | 2:3 (0:1) |
| Cancún |
Copa Libertadores 2001, Preliminary Round |
| 25.10.2000 | | Deportivo Táchira | | Deportivo Italchacao | | 0:2 (0:0) |
| San Cristóbal |
Copa Libertadores 2001, Preliminary Round |
| 26.09.2000 | | Deportivo Italchacao | | Atlante | | 2:0 (2:0) |
| Caracas |
Copa Libertadores 2000, Preliminary Round |
| 29.09.1999 | | Deportivo Táchira | | Deportivo Italchacao | | 0:2 (0:2) |
| Caracas |
Copa Libertadores 1972, First Round, Group 5 |
| 04.03.1972 | | Deportivo Italia | | Carabobo | | 2:0 (1:0) |
| Caracas |
Copa Libertadores 1971, First Round, Group 3 |
| 14.03.1971 | | Deportivo Italia | | Galicia de Aragua | | 3:2 (1:1) |
| Caracas |
Copa Libertadores 1971, First Round, Group 3 |
| 03.03.1971 | | Fluminense | | Deportivo Italia | | 0:1 (0:0) |
| Rio de Janeiro |
Copa Libertadores 1969, Second round, group 1 |
| 15.04.1969 | | Deportivo Italia | | Universidad Católica | | 3:2 (1:0) |
| Caracas |
Copa Libertadores 1969, First Round, Group 1 |
| 05.03.1969 | | Deportivo Italia | | Unión Magdalena | | 2:0 (0:0) |
| Caracas |
Copa Libertadores 1969, First Round, Group 1 |
| 01.03.1969 | | Deportivo Italia | | Deportivo Cali | | 2:1 (1:0) |
| Caracas |
Copa Libertadores 1969, First Round, Group 1 |
| 23.02.1969 | | Deportivo Italia | | Canarias | | 2:0 (2:0) |
| Caracas |
Copa Libertadores 1967, First Round, Group 1 |
| 11.02.1967 | | Deportivo Italia | | Galicia de Aragua | | 1:0 (0:0) |
| Caracas |
Copa Libertadores 1966, First Round, Group 1 |
| 17.03.1966 | | Deportivo Italia | | Lara | | 1:0 (1:0) |
| Caracas |
Copa Libertadores 1966, First Round, Group 1 |
| 13.03.1966 | | Universitario de Deportes | | Deportivo Italia | | 1:2 (0:1) |
| Lima |
Copa Libertadores 1966, First Round, Group 1 |
| 01.03.1966 | | Alianza Lima | | Deportivo Italia | | 1:2 (1:1) |
| Lima |
Copa Libertadores 1966, First Round, Group 1 |
| 12.02.1966 | | Deportivo Italia | | Alianza Lima | | 3:1 (1:0) |
| Caracas |
Copa Libertadores 1964, Group 3 |
| 03.05.1964 | | Barcelona | | Deportivo Italia | | 0:1 (0:0) |
| Guayaquil |
Copa Libertadores 1964, Preliminary Round |
| 07.04.1964 | | Bahia | | Deportivo Italia | | 1:2 (0:0) |
| Venezuela, Caracas |