Copa Libertadores 2024, Group B |
 | 29.05.2024 | | Barcelona | – | Cobresal | | 2:1 (2:0) |
| Guayaquil |
Copa Libertadores 2023, Group C |
| 19.04.2023 | | Barcelona | – | Bolívar | | 2:1 (1:0) |
| Guayaquil |
Copa Libertadores 2022, Second round |
| 02.03.2022 | | Universitario de Deportes | – | Barcelona | | 0:1 (0:0) |
| Lima |
Copa Libertadores 2022, Second round |
| 23.02.2022 | | Barcelona | – | Universitario de Deportes | | 2:0 (0:0) |
| Guayaquil |
Copa Libertadores 2021, Round of 16 |
| 21.07.2021 | | Barcelona | – | Vélez Sársfield | | 3:1 (1:0) |
| Guayaquil |
Copa Libertadores 2021, Group C |
| 26.05.2021 | | Barcelona | – | Santos | | 3:1 (1:1) * |
| Guayaquil |
Copa Libertadores 2021, Group C |
| 04.05.2021 | | Barcelona | – | Boca Juniors | | 1:0 (0:0) * |
| Guayaquil |
Copa Libertadores 2021, Group C |
| 28.04.2021 | | Barcelona | – | The Strongest | | 4:0 (0:0) * |
| Guayaquil |
Copa Libertadores 2021, Group C |
| 20.04.2021 | | Santos | – | Barcelona | | 0:2 (0:0) * |
| Santos |
Copa Libertadores 2020, Group A |
| 30.09.2020 | | Junior | – | Barcelona | | 0:2 (0:1) |
| Barranquilla |
Copa Libertadores 2020, Third qualifying stage |
| 26.02.2020 | | Cerro Porteño | – | Barcelona | | 0:4 (0:1) |
| Asunción |
Copa Libertadores 2020, Third qualifying stage |
| 19.02.2020 | | Barcelona | – | Cerro Porteño | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 2020, Second qualifying stage |
| 06.02.2020 | | Barcelona | – | Sporting Cristal | | 4:0 (2:0) |
| Guayaquil |
Copa Libertadores 2020, First qualifying stage |
| 29.01.2020 | | Barcelona | – | Progreso | | 3:1 (1:0) |
| Guayaquil |
Copa Libertadores 2020, First qualifying stage |
| 22.01.2020 | | Progreso | – | Barcelona | | 0:2 (0:1) |
| Montevideo |
Copa Libertadores 2019, Second qualifying stage |
| 12.02.2019 | | Barcelona | – | Defensor Sporting | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 2017, Semifinal |
| 01.11.2017 | | Grêmio | – | Barcelona | | 0:1 (0:1) |
| Porto Alegre |
Copa Libertadores 2017, Quarterfinal |
| 20.09.2017 | | Santos | – | Barcelona | | 0:1 (0:0) |
| Santos |
Copa Libertadores 2017, Round of 16 |
| 05.07.2017 | | Barcelona | – | Palmeiras | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 2017, Group 1 |
| 02.05.2017 | | Botafogo | – | Barcelona | | 0:2 (0:2) |
| Rio de Janeiro |
Copa Libertadores 2017, Group 1 |
| 11.04.2017 | | Estudiantes | – | Barcelona | | 0:2 (0:0) |
| La Plata |
Copa Libertadores 2017, Group 1 |
| 14.03.2017 | | Barcelona | – | Atlético Nacional | | 2:1 (2:1) |
| Guayaquil |
Copa Libertadores 2015, Group 7 |
| 19.03.2015 | | Atlético Nacional | – | Barcelona | | 2:3 (1:1) |
| Medellín |
Copa Libertadores 2013, Group 1 |
| 17.04.2013 | | Barcelona | – | Nacional Montevideo | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 2004, Playoff |
| 29.04.2004 | | Barcelona | – | Unión Atlético | | 6:1 (3:1) |
| Guayaquil |
Copa Libertadores 2004, Group 7 |
| 14.04.2004 | | Barcelona | – | Guaraní Asunción | | 2:0 (1:0) |
| Guayaquil |
Copa Libertadores 2004, Group 7 |
| 12.02.2004 | | Barcelona | – | Jorge Wilstermann | | 4:0 (1:0) |
| Guayaquil |
Copa Libertadores 2003, Group 7 |
| 06.02.2003 | | Barcelona | – | Colo-Colo | | 2:0 (1:0) |
| Guayaquil |
Copa Libertadores 1998, Semifinal |
| 16.07.1998 | | Barcelona | – | Cerro Porteño | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 1998, Quarterfinal |
| 27.05.1998 | | Barcelona | – | Bolívar | | 4:0 (2:0) |
| Guayaquil |
Copa Libertadores 1998, 1/8 finals |
| 15.04.1998 | | Barcelona | – | Colo-Colo | | 2:1 (1:0) |
| Guayaquil |
Copa Libertadores 1998, Group 1 |
| 13.03.1998 | | Barcelona | – | América de Cali | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 1998, Group 1 |
| 06.03.1998 | | Barcelona | – | Atlético Bucaramanga | | 2:0 (2:0) |
| Guayaquil |
Copa Libertadores 1996, 1/8 finals |
| 08.05.1996 | | Barcelona | – | San José | | 2:1 (0:0),
pen. 4:2 |
| Guayaquil |
Copa Libertadores 1996, Group 1 |
| 03.04.1996 | | Espoli | – | Barcelona | | 1:2 (0:0) |
| Quito |
Copa Libertadores 1996, Group 1 |
| 29.03.1996 | | Barcelona | – | Cerro Porteño | | 3:2 (1:1) |
| Guayaquil |
Copa Libertadores 1996, Group 1 |
| 22.03.1996 | | Barcelona | – | Olimpia | | 2:1 (1:1) |
| Guayaquil |
Copa Libertadores 1996, Group 1 |
| 13.03.1996 | | Barcelona | – | Espoli | | 3:2 (0:0) |
| Guayaquil |
Copa Libertadores 1994, Group 3 |
| 15.03.1994 | | Barcelona | – | Alianza Lima | | 3:0 (0:0) |
| Guayaquil |
Copa Libertadores 1994, Group 3 |
| 02.03.1994 | | Emelec | – | Barcelona | | 0:1 (0:1) |
| Guayaquil |
Copa Libertadores 1993, 1/8 finals |
| 14.04.1993 | | Barcelona | – | Universitario de Deportes | | 3:0 |
| Guayaquil |
Copa Libertadores 1993, Group 3 |
| 10.03.1993 | | Barcelona | – | El Nacional | | 4:0 (3:0) |
| Guayaquil |
Copa Libertadores 1993, Group 3 |
| 23.02.1993 | | Barcelona | – | Bella Vista | | 2:0 (1:0) |
| Guayaquil |
Copa Libertadores 1992, Semifinal |
| 03.06.1992 | | Barcelona | – | São Paulo | | 2:0 (0:0) |
| Guayaquil |
Copa Libertadores 1992, 1/8 finals |
| 06.05.1992 | | Barcelona | – | Colo-Colo | | 2:0 (0:0) |
| Guayaquil |
Copa Libertadores 1992, Group 3 |
| 10.04.1992 | | Barcelona | – | Universidad de Los Andes | | 5:1 (3:0) |
| Guayaquil |
Copa Libertadores 1992, Group 3 |
| 03.04.1992 | | Barcelona | – | Marítimo | | 3:1 (2:0) |
| Guayaquil |
Copa Libertadores 1992, Group 3 |
| 29.03.1992 | | Filanbanco | – | Barcelona | | 0:1 (0:1) |
| Guayaquil |
Copa Libertadores 1992, Group 3 |
| 22.03.1992 | | Universidad de Los Andes | – | Barcelona | | 0:1 (0:0) |
| Mérida |
Copa Libertadores 1990, Semifinal |
| 12.09.1990 | | Barcelona | – | River Plate | | 1:0 (1:0),
pen. 4:3 |
| Guayaquil |
Copa Libertadores 1990, Quarterfinal |
| 29.08.1990 | | Barcelona | – | Emelec | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 1990, 1/8 finals |
| 08.08.1990 | | Barcelona | – | Progreso | | 2:0 (1:0) |
| Guayaquil |
Copa Libertadores 1990, Group 1 |
| 09.05.1990 | | Barcelona | – | Oriente Petrolero | | 3:1 (1:1) * |
| Guayaquil |
Copa Libertadores 1990, Group 1 |
| 17.04.1990 | | Barcelona | – | The Strongest | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 1990, Group 1 |
| 27.03.1990 | | Barcelona | – | Oriente Petrolero | | 2:1 (2:0) |
| Guayaquil |
Copa Libertadores 1988, Group 2 |
| 20.07.1988 | | Filanbanco | – | Barcelona | | 1:2 (1:1) |
| Milagro |
Copa Libertadores 1988, Group 2 |
| 13.07.1988 | | Barcelona | – | San Lorenzo de Almagro | | 2:0 (2:0) |
| Guayaquil |
Copa Libertadores 1988, Group 2 |
| 06.07.1988 | | Barcelona | – | Filanbanco | | 4:2 (1:1) |
| Guayaquil |
Copa Libertadores 1987, First Round, Group 4 |
| 24.05.1987 | | Barcelona | – | Olimpia | | 3:2 (1:0) |
| Guayaquil |
Copa Libertadores 1987, First Round, Group 4 |
| 20.05.1987 | | Barcelona | – | Sol de América | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 1987, First Round, Group 4 |
| 14.05.1987 | | Barcelona | – | El Nacional | | 2:1 (1:1) * |
| Guayaquil |
Copa Libertadores 1987, First Round, Group 4 |
| 08.04.1987 | | Sol de América | – | Barcelona | | 1:2 (0:0) |
| Asunción |
Copa Libertadores 1986, Semifinal group 1 |
| 11.09.1986 | | Barcelona | – | Argentinos Juniors | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 1986, First Round, Group 4 |
| 15.07.1986 | | Bangu | – | Barcelona | | 1:2 (1:0) |
| Rio de Janeiro |
Copa Libertadores 1986, First Round, Group 4 |
| 01.05.1986 | | Barcelona | – | Bangu | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 1983, First Round, Group 4 |
| 24.04.1983 | | Barcelona | – | El Nacional | | 2:0 (1:0) |
| Guayaquil |
Copa Libertadores 1982, First Round, Group 4 |
| 07.03.1982 | | Barcelona | – | LDU | | 4:1 (2:0) |
| Guayaquil |
Copa Libertadores 1981, First Round, Group 4 |
| 08.04.1981 | | Barcelona | – | Jorge Wilstermann | | 3:0 (1:0) |
| Guayaquil |
Copa Libertadores 1981, First Round, Group 4 |
| 05.04.1981 | | Barcelona | – | The Strongest | | 2:1 (2:1) |
| Guayaquil |
Copa Libertadores 1981, First Round, Group 4 |
| 29.03.1981 | | Barcelona | – | Técnico Universitario | | 2:1 (0:0) |
| Guayaquil |
Copa Libertadores 1972, First Round, Group 2 |
| 22.03.1972 | | Barcelona | – | Chaco Petrolero | | 3:0 (1:0) |
| Guayaquil |
Copa Libertadores 1972, First Round, Group 2 |
| 12.03.1972 | | Chaco Petrolero | – | Barcelona | | 1:2 (0:2) |
| La Paz |
Copa Libertadores 1972, First Round, Group 2 |
| 27.02.1972 | | Barcelona | – | América Quito | | 2:1 (0:0) |
| Guayaquil |
Copa Libertadores 1971, Semifinal group 2 |
| 29.04.1971 | | Estudiantes La Plata | – | Barcelona | | 0:1 (0:0) |
| La Plata |
Copa Libertadores 1971, Semifinal group 2 |
| 25.04.1971 | | Barcelona | – | Unión Española | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 1971, First Round, Group 5 |
| 31.03.1971 | | Barcelona | – | Emelec | | 3:0 (1:0) * |
| Guayaquil |
Copa Libertadores 1971, First Round, Group 5 |
| 18.03.1971 | | Junior | – | Barcelona | | 0:2 (0:0) |
| Barranquilla |
Copa Libertadores 1971, First Round, Group 5 |
| 07.03.1971 | | Barcelona | – | Junior | | 3:1 (0:0) |
| Guayaquil |
Copa Libertadores 1971, First Round, Group 5 |
| 03.03.1971 | | Barcelona | – | Deportivo Cali | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 1967, First Round, Group 3 |
| 08.05.1967 | | Barcelona | – | Emelec | | 2:1 (1:0) |
| Guayaquil |
Copa Libertadores 1967, First Round, Group 3 |
| 05.04.1967 | | Cerro Porteño | – | Barcelona | | 1:2 (1:0) |
| |
Copa Libertadores 1967, First Round, Group 3 |
| 05.03.1967 | | Barcelona | – | Guaraní Asunción | | 2:1 (2:1) |
| Guayaquil |
Copa Libertadores 1967, First Round, Group 3 |
| 26.02.1967 | | Barcelona | – | Nacional Montevideo | | 2:1 (2:0) |
| Guayaquil |
Copa Libertadores 1964, Group 3 |
| 28.05.1964 | | Colo-Colo | – | Barcelona | | 0:4 (0:1) |
| Santiago |
Copa Libertadores 1964, Group 3 |
| 24.05.1964 | | Deportivo Italia | – | Barcelona | | 0:3 (0:0) |
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