Copa Libertadores 2024, Group B |
 | 08.05.2024 | | Talleres | – | Barcelona | | 3:1 (2:0) |
| Córdoba |
Copa Libertadores 2024, Group B |
| 25.04.2024 | | Barcelona | – | São Paulo | | 0:2 (0:1) |
| Guayaquil |
Copa Libertadores 2023, Group C |
| 07.06.2023 | | Palmeiras | – | Barcelona | | 4:2 (0:2) |
| São Paulo |
Copa Libertadores 2023, Group C |
| 23.05.2023 | | Bolívar | – | Barcelona | | 1:0 (0:0) |
| La Paz |
Copa Libertadores 2023, Group C |
| 03.05.2023 | | Barcelona | – | Palmeiras | | 0:2 (0:1) |
| Guayaquil |
Copa Libertadores 2023, Group C |
| 05.04.2023 | | Cerro Porteño | – | Barcelona | | 2:1 (1:0) |
| Asunción |
Copa Libertadores 2021, Semifinal |
| 29.09.2021 | | Barcelona | – | Flamengo | | 0:2 (0:1) |
| Guayaquil |
Copa Libertadores 2021, Semifinal |
| 22.09.2021 | | Flamengo | – | Barcelona | | 2:0 (2:0) |
| Rio de Janeiro |
Copa Libertadores 2021, Round of 16 |
| 14.07.2021 | | Vélez Sársfield | – | Barcelona | | 1:0 (1:0) |
| Buenos Aires |
Copa Libertadores 2021, Group C |
| 11.05.2021 | | The Strongest | – | Barcelona | | 2:0 (1:0) * |
| La Paz |
Copa Libertadores 2020, Group A |
| 21.10.2020 | | Independiente del Valle | – | Barcelona | | 2:0 (1:0) |
| Quito |
Copa Libertadores 2020, Group A |
| 22.09.2020 | | Barcelona | – | Flamengo | | 1:2 (0:2) |
| Guayaquil |
Copa Libertadores 2020, Group A |
| 17.09.2020 | | Barcelona | – | Junior | | 1:2 (1:1) |
| Guayaquil |
Copa Libertadores 2020, Group A |
| 11.03.2020 | | Flamengo | – | Barcelona | | 3:0 (2:0) |
| Rio de Janeiro |
Copa Libertadores 2020, Group A |
| 04.03.2020 | | Barcelona | – | Independiente del Valle | | 0:3 (0:0) |
| Guayaquil |
Copa Libertadores 2020, Second qualifying stage |
| 13.02.2020 | | Sporting Cristal | – | Barcelona | | 2:1 (0:0) |
| Lima |
Copa Libertadores 2019, Second qualifying stage |
| 06.02.2019 | | Defensor Sporting | – | Barcelona | | 3:0 |
| Montevideo |
Copa Libertadores 2017, Semifinal |
| 25.10.2017 | | Barcelona | – | Grêmio | | 0:3 (0:2) |
| Guayaquil |
Copa Libertadores 2017, Round of 16 |
| 09.08.2017 | | Palmeiras | – | Barcelona | | 1:0 (0:0),
pen. 4:5 |
| São Paulo |
Copa Libertadores 2017, Group 1 |
| 25.05.2017 | | Atlético Nacional | – | Barcelona | | 3:1 (2:1) |
| Medellín |
Copa Libertadores 2017, Group 1 |
| 18.05.2017 | | Barcelona | – | Estudiantes | | 0:3 (0:1) |
| Guayaquil |
Copa Libertadores 2015, Group 7 |
| 21.04.2015 | | Barcelona | – | Estudiantes | | 0:2 (0:0) |
| Guayaquil |
Copa Libertadores 2015, Group 7 |
| 11.03.2015 | | Barcelona | – | Atlético Nacional | | 1:2 (1:0) |
| Guayaquil |
Copa Libertadores 2015, Group 7 |
| 03.03.2015 | | Barcelona | – | Libertad | | 0:1 (0:0) |
| Guayaquil |
Copa Libertadores 2015, Group 7 |
| 25.02.2015 | | Estudiantes | – | Barcelona | | 3:0 (2:0) |
| La Plata |
Copa Libertadores 2013, Group 1 |
| 03.04.2013 | | Boca Juniors | – | Barcelona | | 1:0 (1:0) |
| Buenos Aires |
Copa Libertadores 2013, Group 1 |
| 27.02.2013 | | Barcelona | – | Boca Juniors | | 1:2 (0:0) |
| Guayaquil |
Copa Libertadores 2004, Group 7 |
| 11.03.2004 | | Santos | – | Barcelona | | 1:0 (0:0) |
| Santos |
Copa Libertadores 2004, Group 7 |
| 03.03.2004 | | Barcelona | – | Santos | | 1:3 (0:1) |
| Guayaquil |
Copa Libertadores 2003, Group 7 |
| 03.04.2003 | | Barcelona | – | Independiente Medellín | | 2:4 (1:2) |
| Guayaquil |
Copa Libertadores 2003, Group 7 |
| 05.03.2003 | | Boca Juniors | – | Barcelona | | 2:1 (1:0) |
| Buenos Aires |
Copa Libertadores 2003, Group 7 |
| 27.02.2003 | | Independiente Medellín | – | Barcelona | | 1:0 (1:0) |
| Medellín |
Copa Libertadores 1998, Final |
| 26.08.1998 | | Barcelona | – | Vasco da Gama | | 1:2 (0:2) |
| Guayaquil |
Copa Libertadores 1998, Final |
| 12.08.1998 | | Vasco da Gama | – | Barcelona | | 2:0 (2:0) |
| Rio de Janeiro |
Copa Libertadores 1998, Semifinal |
| 22.07.1998 | | Cerro Porteño | – | Barcelona | | 2:1 (2:0),
pen. 3:4 |
| Asunción |
Copa Libertadores 1998, Group 1 |
| 31.03.1998 | | Atlético Bucaramanga | – | Barcelona | | 1:0 (1:0) |
| Bucaramanga |
Copa Libertadores 1996, Quarterfinal |
| 15.05.1996 | | Universidad de Chile | – | Barcelona | | 2:0 (0:0) |
| Santiago |
Copa Libertadores 1996, 1/8 finals |
| 01.05.1996 | | San José | – | Barcelona | | 1:0 (1:0) |
| Oruro |
Copa Libertadores 1996, Group 1 |
| 16.04.1996 | | Cerro Porteño | – | Barcelona | | 1:0 (0:0) |
| Asunción |
Copa Libertadores 1994, 1/8 finals |
| 27.04.1994 | | Olimpia | – | Barcelona | | 2:1 (1:0) |
| Asunción |
Copa Libertadores 1994, 1/8 finals |
| 20.04.1994 | | Barcelona | – | Olimpia | | 0:1 (0:1) |
| Guayaquil |
Copa Libertadores 1994, Group 3 |
| 05.04.1994 | | Alianza Lima | – | Barcelona | | 2:1 (1:0) |
| Lima |
Copa Libertadores 1994, Group 3 |
| 23.03.1994 | | Barcelona | – | Emelec | | 0:1 (0:0) |
| Guayaquil |
Copa Libertadores 1993, Quarterfinal |
| 28.04.1993 | | Barcelona | – | Universidad Católica | | 0:1 (0:1) |
| Guayaquil |
Copa Libertadores 1993, Quarterfinal |
| 21.04.1993 | | Universidad Católica | – | Barcelona | | 3:1 (2:0) |
| Santiago |
Copa Libertadores 1993, 1/8 finals |
| 07.04.1993 | | Universitario de Deportes | – | Barcelona | | 2:1 (1:0) |
| Lima |
Copa Libertadores 1993, Group 3 |
| 19.03.1993 | | Nacional Montevideo | – | Barcelona | | 3:0 (1:0) |
| Montevideo |
Copa Libertadores 1993, Group 3 |
| 16.03.1993 | | Bella Vista | – | Barcelona | | 2:1 (1:1) |
| Montevideo |
Copa Libertadores 1993, Group 3 |
| 17.02.1993 | | El Nacional | – | Barcelona | | 1:0 (1:0) |
| Quito |
Copa Libertadores 1992, Semifinal |
| 27.05.1992 | | São Paulo | – | Barcelona | | 3:0 (3:0) |
| São Paulo |
Copa Libertadores 1992, 1/8 finals |
| 30.04.1992 | | Colo-Colo | – | Barcelona | | 1:0 (0:0) |
| Santiago |
Copa Libertadores 1991, Group 2 |
| 01.03.1991 | | Colo-Colo | – | Barcelona | | 3:1 (2:0) |
| Santiago |
Copa Libertadores 1991, Group 2 |
| 26.02.1991 | | Concepción | – | Barcelona | | 1:0 (1:0) |
| Concepción |
Copa Libertadores 1991, Group 2 |
| 20.02.1991 | | Barcelona | – | LDU | | 0:1 (0:0) |
| Guayaquil |
Copa Libertadores 1990, Final |
| 03.10.1990 | | Olimpia | – | Barcelona | | 2:0 (0:0) |
| Asunción |
Copa Libertadores 1990, Semifinal |
| 05.09.1990 | | River Plate | – | Barcelona | | 1:0 (0:0) |
| Buenos Aires |
Copa Libertadores 1990, Group 1 |
| 16.05.1990 | | Oriente Petrolero | – | Barcelona | | 3:2 (2:2),
pen. 4:5 * |
| Santa Cruz de la Sierra |
Copa Libertadores 1990, Group 1 |
| 10.04.1990 | | The Strongest | – | Barcelona | | 2:1 (2:1) |
| La Paz |
Copa Libertadores 1990, Group 1 |
| 04.04.1990 | | Emelec | – | Barcelona | | 3:1 (3:0) |
| Guayaquil |
Copa Libertadores 1988, Group 2 |
| 01.08.1988 | | Newell's Old Boys | – | Barcelona | | 3:0 (1:0) |
| Rosario |
Copa Libertadores 1988, Group 2 |
| 27.07.1988 | | San Lorenzo de Almagro | – | Barcelona | | 2:1 (2:1) |
| Buenos Aires |
Copa Libertadores 1987, Semifinal group 1 |
| 23.09.1987 | | América de Cali | – | Barcelona | | 4:0 (2:0) |
| Santiago de Cali |
Copa Libertadores 1987, Semifinal group 1 |
| 15.09.1987 | | Barcelona | – | Cobreloa | | 0:2 (0:0) |
| Guayaquil |
Copa Libertadores 1987, Semifinal group 1 |
| 09.09.1987 | | Barcelona | – | América de Cali | | 0:2 (0:1) |
| Guayaquil |
Copa Libertadores 1987, Semifinal group 1 |
| 01.09.1987 | | Cobreloa | – | Barcelona | | 3:0 (2:0) |
| Calama |
Copa Libertadores 1987, First Round, Group 4 |
| 12.04.1987 | | Olimpia | – | Barcelona | | 1:0 (0:0) |
| Asunción |
Copa Libertadores 1987, First Round, Group 4 |
| 22.03.1987 | | El Nacional | – | Barcelona | | 2:0 (1:0) |
| Quito |
Copa Libertadores 1986, Semifinal group 1 |
| 30.09.1986 | | Argentinos Juniors | – | Barcelona | | 1:0 (0:0) |
| Buenos Aires |
Copa Libertadores 1986, Semifinal group 1 |
| 23.09.1986 | | River Plate | – | Barcelona | | 4:1 (4:0) |
| Buenos Aires |
Copa Libertadores 1986, Semifinal group 1 |
| 16.09.1986 | | Barcelona | – | River Plate | | 0:3 (0:2) |
| Guayaquil |
Copa Libertadores 1983, First Round, Group 4 |
| 04.04.1983 | | Atlético San Cristóbal | – | Barcelona | | 2:0 (1:0) * |
| San Cristóbal |
Copa Libertadores 1983, First Round, Group 4 |
| 27.03.1983 | | El Nacional | – | Barcelona | | 3:1 (1:1) |
| Quito |
Copa Libertadores 1982, First Round, Group 4 |
| 10.09.1982 | | Colo-Colo | – | Barcelona | | 2:0 (0:0) |
| Santiago |
Copa Libertadores 1982, First Round, Group 4 |
| 07.09.1982 | | Cobreloa | – | Barcelona | | 3:0 (2:0) |
| Calama |
Copa Libertadores 1982, First Round, Group 4 |
| 22.08.1982 | | Barcelona | – | Colo-Colo | | 1:3 (0:1) |
| Guayaquil |
Copa Libertadores 1982, First Round, Group 4 |
| 14.03.1982 | | LDU | – | Barcelona | | 4:2 (2:0) |
| Quito |
Copa Libertadores 1981, First Round, Group 4 |
| 26.04.1981 | | Técnico Universitario | – | Barcelona | | 4:1 (0:0) |
| Ambato |
Copa Libertadores 1981, First Round, Group 4 |
| 19.04.1981 | | Jorge Wilstermann | – | Barcelona | | 1:0 (1:0) |
| Cochabamba |
Copa Libertadores 1981, First Round, Group 4 |
| 12.04.1981 | | The Strongest | – | Barcelona | | 1:0 (0:0) |
| La Paz |
Copa Libertadores 1972, Semifinal group 2 |
| 18.04.1972 | | Independiente Avellaneda | – | Barcelona | | 1:0 (1:0) |
| Avellaneda |
Copa Libertadores 1971, Semifinal group 2 |
| 05.05.1971 | | Unión Española | – | Barcelona | | 3:1 (2:0) |
| Santiago |
Copa Libertadores 1971, Semifinal group 2 |
| 18.04.1971 | | Barcelona | – | Estudiantes La Plata | | 0:1 (0:1) |
| Guayaquil |
Copa Libertadores 1971, First Round, Group 5 |
| 21.03.1971 | | Deportivo Cali | – | Barcelona | | 3:1 (0:0) |
| Santiago de Cali |
Copa Libertadores 1971, First Round, Group 5 |
| 28.02.1971 | | Barcelona | – | Emelec | | 0:1 (0:0) |
| Guayaquil |
Copa Libertadores 1969, First Round, Group 4 |
| 15.03.1969 | | Peñarol | – | Barcelona | | 5:2 (3:1) |
| Montevideo |
Copa Libertadores 1969, First Round, Group 4 |
| 13.03.1969 | | Nacional Montevideo | – | Barcelona | | 2:0 (1:0) |
| Montevideo |
Copa Libertadores 1969, First Round, Group 4 |
| 26.02.1969 | | Barcelona | – | Peñarol | | 0:2 (0:1) |
| Guayaquil |
Copa Libertadores 1969, First Round, Group 4 |
| 23.02.1969 | | Deportivo Quito | – | Barcelona | | 1:0 (1:0) |
| Quito |
Copa Libertadores 1967, First Round, Group 3 |
| 26.04.1967 | | Barcelona | – | Universidad Católica | | 0:2 (0:1) |
| Guayaquil |
Copa Libertadores 1967, First Round, Group 3 |
| 02.04.1967 | | Guaraní Asunción | – | Barcelona | | 4:1 (2:1) |
| Asunción |
Copa Libertadores 1967, First Round, Group 3 |
| 25.03.1967 | | Universidad Católica | – | Barcelona | | 3:1 (1:0) |
| Santiago |
Copa Libertadores 1967, First Round, Group 3 |
| 22.03.1967 | | Colo-Colo | – | Barcelona | | 3:2 (2:2) |
| Santiago |
Copa Libertadores 1967, First Round, Group 3 |
| 17.03.1967 | | Nacional Montevideo | – | Barcelona | | 2:0 (1:0) |
| Montevideo |
Copa Libertadores 1967, First Round, Group 3 |
| 09.03.1967 | | Barcelona | – | Cerro Porteño | | 1:2 (0:2) |
| Guayaquil |
Copa Libertadores 1967, First Round, Group 3 |
| 12.02.1967 | | Emelec | – | Barcelona | | 3:0 (2:0) |
| Guayaquil |
Copa Libertadores 1964, Group 3 |
| 13.05.1964 | | Barcelona | – | Colo-Colo | | 2:3 (0:1) |
| Guayaquil |
Copa Libertadores 1964, Group 3 |
| 03.05.1964 | | Barcelona | – | Deportivo Italia | | 0:1 (0:0) |
| Guayaquil |
Copa Libertadores 1961, First Round |
| 02.04.1961 | | Santa Fe | – | Barcelona | | 3:0 (0:0) |
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