Copa Libertadores 2022, Group E |
 | 26.05.2022 |  | Boca Juniors | – | Deportivo Cali |  | 1:0 (0:0) |
| Buenos Aires |
Copa Libertadores 2022, Group E |
| 13.04.2022 |  | Corinthians | – | Deportivo Cali | | 1:0 (0:0) |
| São Paulo |
Copa Libertadores 2016, Group 3 |
| 20.04.2016 | | Boca Juniors | – | Deportivo Cali | | 6:2 (2:2) |
| Buenos Aires |
Copa Libertadores 2016, Group 3 |
| 07.04.2016 | | Racing Club | – | Deportivo Cali | | 4:2 (3:0) |
| Avellaneda |
Copa Libertadores 2016, Group 3 |
| 03.03.2016 |  | Bolívar | – | Deportivo Cali | | 5:0 (3:0) |
| La Paz |
Copa Libertadores 2014, Group 3 |
| 08.04.2014 |  | Cerro Porteño | – | Deportivo Cali | | 3:2 (2:1) |
| Asunción |
Copa Libertadores 2014, Group 3 |
| 20.03.2014 | | Lanús | – | Deportivo Cali | | 2:0 (2:0) |
| Lanús |
Copa Libertadores 2014, Group 3 |
| 19.02.2014 |  | O'Higgins | – | Deportivo Cali | | 1:0 (0:0) |
| Rancagua |
Copa Libertadores 2006, Group 4 |
| 19.04.2006 | | Corinthians | – | Deportivo Cali | | 3:0 (2:0) |
| São Paulo |
Copa Libertadores 2006, Group 4 |
| 30.03.2006 | | Deportivo Cali | – | Universidad Católica | | 2:3 (1:1) |
| Santiago de Cali |
Copa Libertadores 2006, Group 4 |
| 21.03.2006 | | Universidad Católica | – | Deportivo Cali | | 2:1 (1:1) |
| Santiago |
Copa Libertadores 2006, Group 4 |
| 21.02.2006 |  | Sinergia Deportiva | – | Deportivo Cali | | 5:4 (2:3) |
| Monterrey |
Copa Libertadores 2006, Group 4 |
| 15.02.2006 | | Deportivo Cali | – | Corinthians | | 0:1 (0:0) |
| Santiago de Cali |
Copa Libertadores 2004, Quarterfinal |
| 26.05.2004 | | Deportivo Cali | – | River Plate | | 1:3 (1:2) |
| Santiago de Cali |
Copa Libertadores 2004, Quarterfinal |
| 20.05.2004 | | River Plate | – | Deportivo Cali | | 1:0 (1:0) |
| Buenos Aires |
Copa Libertadores 2004, 1/8 finals |
| 13.05.2004 | | Cruzeiro | – | Deportivo Cali | | 2:1 (1:0),
pen. 0:3 |
| Belo Horizonte |
Copa Libertadores 2004, Group 8 |
| 07.04.2004 | | Bolívar | – | Deportivo Cali | | 1:0 (1:0) |
| La Paz |
Copa Libertadores 2004, Group 8 |
| 24.03.2004 | | Boca Juniors | – | Deportivo Cali | | 3:0 (0:0) |
| Buenos Aires |
Copa Libertadores 2004, Group 8 |
| 10.03.2004 | | Deportivo Cali | – | Boca Juniors | | 0:1 (0:0) |
| Santiago de Cali |
Copa Libertadores 2003, Group 1 |
| 17.04.2003 | | Libertad | – | Deportivo Cali | | 1:0 (1:0) |
| Asunción |
Copa Libertadores 2003, Group 1 |
| 20.03.2003 | | River Plate | – | Deportivo Cali | | 2:1 (1:1) |
| Buenos Aires |
Copa Libertadores 2001, Group 8 |
| 04.04.2001 | | Cobreloa | – | Deportivo Cali | | 2:1 (1:0) |
| Calama |
Copa Libertadores 2001, Group 8 |
| 07.03.2001 | | Boca Juniors | – | Deportivo Cali | | 2:1 (1:1) |
| Buenos Aires |
Copa Libertadores 2001, Group 8 |
| 14.02.2001 | | Deportivo Cali | – | Cobreloa | | 1:2 (1:1) |
| Santiago de Cali |
Copa Libertadores 1999, Group 2 |
| 08.08.1999 | | Vélez Sársfield | – | Deportivo Cali | | 3:0 (2:0) |
| Buenos Aires |
Copa Libertadores 1999, Group 2 |
| 06.08.1999 | | River Plate | – | Deportivo Cali | | 2:1 (2:1) |
| Buenos Aires |
Copa Libertadores 1999, Final |
| 16.06.1999 | | Palmeiras | – | Deportivo Cali | | 2:1 (0:0),
pen. 4:3 |
| São Paulo |
Copa Libertadores 1999, Semifinal |
| 26.05.1999 | | Cerro Porteño | – | Deportivo Cali | | 3:2 (1:1) |
| Asunción |
Copa Libertadores 1999, 1/8 finals |
| 21.04.1999 | | Colo-Colo | – | Deportivo Cali | | 1:0 (0:0) |
| Santiago |
Copa Libertadores 1999, Group 2 |
| 17.03.1999 | | Once Caldas | – | Deportivo Cali | | 3:0 (1:0) |
| Manizales |
Copa Libertadores 1997, Group 5 |
| 18.04.1997 |  | Peñarol | – | Deportivo Cali | | 4:3 (1:2) |
| Montevideo |
Copa Libertadores 1997, Group 5 |
| 08.04.1997 | | Deportivo Cali | – | Nacional Montevideo | | 0:1 (0:1) |
| Santiago de Cali |
Copa Libertadores 1997, Group 5 |
| 27.02.1997 | | Deportivo Cali | – | Los Millonarios | | 1:2 (0:2) |
| Santiago de Cali |
Copa Libertadores 1987, First Round, Group 2 |
| 12.05.1987 | | The Strongest | – | Deportivo Cali | | 2:1 (1:1) |
| La Paz |
Copa Libertadores 1987, First Round, Group 2 |
| 07.05.1987 | | América de Cali | – | Deportivo Cali | | 1:0 (0:0) |
| Santiago de Cali |
Copa Libertadores 1986, First Round, Group 2 |
| 10.04.1986 | | Deportivo Cali | – | América de Cali | | 0:1 (0:0) |
| Santiago de Cali |
Copa Libertadores 1981, Semifinal group 1 |
| 23.10.1981 | | Flamengo | – | Deportivo Cali | | 3:0 (1:0) |
| Rio de Janeiro |
Copa Libertadores 1981, Semifinal group 1 |
| 02.10.1981 | | Deportivo Cali | – | Flamengo | | 0:1 (0:1) |
| Santiago de Cali |
Copa Libertadores 1981, First Round, Group 1 |
| 24.04.1981 | | Rosario Central | – | Deportivo Cali | | 2:1 (1:1) |
| Rosario |
Copa Libertadores 1981, First Round, Group 1 |
| 25.03.1981 | | Junior | – | Deportivo Cali | | 1:0 (0:0) |
| Barranquilla |
Copa Libertadores 1979, First Round, Group 1 |
| 13.04.1979 | | Quilmes | – | Deportivo Cali | | 3:1 (2:0) |
| Quilmes |
Copa Libertadores 1979, First Round, Group 1 |
| 10.04.1979 | | Independiente Avellaneda | – | Deportivo Cali | | 1:0 (1:0) |
| Avellaneda |
Copa Libertadores 1978, Final |
| 28.11.1978 | | Boca Juniors | – | Deportivo Cali | | 4:0 (1:0) |
| Buenos Aires |
Copa Libertadores 1978, First Round, Group 4 |
| 23.07.1978 | | Danubio | – | Deportivo Cali | | 3:0 (1:0) |
| Montevideo |
Copa Libertadores 1977, Semifinal group 1 |
| 10.08.1977 | | Libertad | – | Deportivo Cali | | 2:1 (2:0) |
| Asunción |
Copa Libertadores 1977, First Round, Group 2 |
| 08.05.1977 | | Oriente Petrolero | – | Deportivo Cali | | 1:0 (0:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1977, First Round, Group 2 |
| 04.05.1977 | | Bolívar | – | Deportivo Cali | | 3:0 (1:0) |
| La Paz |
Copa Libertadores 1975, First Round, Group 3 |
| 10.04.1975 | | Cruzeiro | – | Deportivo Cali | | 2:1 (1:0) |
| Belo Horizonte |
Copa Libertadores 1975, First Round, Group 3 |
| 23.03.1975 | | Atlético Nacional | – | Deportivo Cali | | 2:1 (0:1) |
| Medellín |
Copa Libertadores 1973, First Round, Group 4 |
| 15.03.1973 | | Los Millonarios | – | Deportivo Cali | | 6:2 (2:1) |
| Bogotá |
Copa Libertadores 1971, First Round, Group 5 |
| 07.03.1971 |  | Emelec | – | Deportivo Cali | | 3:1 (2:1) |
| Guayaquil |
Copa Libertadores 1971, First Round, Group 5 |
| 03.03.1971 | | Barcelona | – | Deportivo Cali | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 1971, First Round, Group 5 |
| 28.02.1971 | | Junior | – | Deportivo Cali | | 2:1 (1:0) |
| Barranquilla |
Copa Libertadores 1970, First Round, Group 3 |
| 21.03.1970 | | Olimpia | – | Deportivo Cali | | 5:1 (3:1) |
| Asunción |
Copa Libertadores 1970, First Round, Group 3 |
| 15.03.1970 | | Universidad de Chile | – | Deportivo Cali | | 3:1 (0:1) |
| Santiago |
Copa Libertadores 1970, First Round, Group 3 |
| 05.03.1970 | | Deportivo Cali | – | Olimpia | | 0:1 (0:1) |
| Santiago de Cali |
Copa Libertadores 1969, Second round, group 2 |
| 13.04.1969 | | Nacional Montevideo | – | Deportivo Cali | | 2:0 (2:0) |
| Montevideo |
Copa Libertadores 1969, Second round, group 2 |
| 02.04.1969 | | Deportivo Cali | – | Nacional Montevideo | | 1:5 (1:3) |
| Santiago de Cali |
Copa Libertadores 1969, First Round, Group 1 |
| 01.03.1969 |  | Deportivo Italia | – | Deportivo Cali | | 2:1 (1:0) |
| Caracas |
Copa Libertadores 1968, First Round, Group 1 |
| 06.03.1968 | | Independiente Avellaneda | – | Deportivo Cali | | 3:2 (3:0) * |
| Lima |
Copa Libertadores 1968, First Round, Group 1 |
| 17.02.1968 | | Estudiantes La Plata | – | Deportivo Cali | | 3:0 (1:0) |
| La Plata |
Copa Libertadores 1968, First Round, Group 1 |
| 14.02.1968 | | Los Millonarios | – | Deportivo Cali | | 4:2 (1:1) |
| Bogotá |
Copa Libertadores 1968, First Round, Group 1 |
| 11.02.1968 | | Deportivo Cali | – | Estudiantes La Plata | | 1:2 (0:0) |
| Santiago de Cali |
Superclásico
Copa Newton
Copa Lipton
Copa Rosa
Copa Félix Bogado
Copa Carlos Dittborn
Copa Ramón Castilla
Copa Rio Branco
Copa Rodrigues Alves
Taça Bernardo O'Higgins
Copa Artigas
Copa Paz del Chaco
Copa del Pacífico
