Copa Libertadores 2022, Group A |
 | 24.05.2022 |  | Emelec | – | Independiente Petrolero |  | 7:0 (4:0) |
| Guayaquil |
Copa Libertadores 2022, Group A |
| 03.05.2022 |  | Deportivo Táchira | – | Emelec | | 1:4 (1:2) |
| San Cristóbal |
Copa Libertadores 2019, Round of 16 |
| 24.07.2019 | | Emelec | – | Flamengo |  | 2:0 (1:0) |
| Guayaquil |
Copa Libertadores 2019, Group B |
| 08.05.2019 | | Cruzeiro | – | Emelec | | 1:2 (0:1) |
| Belo Horizonte |
Copa Libertadores 2019, Group B |
| 23.04.2019 |  | Huracán | – | Emelec | | 1:2 (0:1) |
| Buenos Aires |
Copa Libertadores 2017, Round of 16 |
| 10.08.2017 | | San Lorenzo de Almagro | – | Emelec | | 0:1 (0:0),
pen. 5:4 |
| Buenos Aires |
Copa Libertadores 2017, Group 3 |
| 25.05.2017 | | Emelec | – | Melgar |  | 3:0 (1:0) |
| Guayaquil |
Copa Libertadores 2017, Group 3 |
| 16.05.2017 |  | Independiente | – | Emelec | | 1:2 (1:2) |
| Medellín |
Copa Libertadores 2017, Group 3 |
| 13.04.2017 | | Emelec | – | Independiente | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 2016, Group 7 |
| 25.02.2016 | | Emelec | – | Deportivo Táchira | | 2:0 (0:0) |
| Guayaquil |
Copa Libertadores 2015, Quarterfinal |
| 19.05.2015 | | Emelec | – | Tigres UANL |  | 1:0 (0:0) |
| Manta |
Copa Libertadores 2015, Round of 16 |
| 07.05.2015 | | Emelec | – | Atlético Nacional | | 2:0 (1:0) |
| Guayaquil |
Copa Libertadores 2015, Group 4 |
| 22.04.2015 | | Emelec | – | Universidad de Chile |  | 2:0 (1:0) |
| Guayaquil |
Copa Libertadores 2015, Group 4 |
| 24.02.2015 | | Emelec | – | The Strongest | | 3:0 (2:0) |
| Guayaquil |
Copa Libertadores 2015, Group 4 |
| 17.02.2015 | | Universidad de Chile | – | Emelec | | 0:1 (0:0) |
| Santiago |
Copa Libertadores 2014, Group 7 |
| 11.03.2014 | | Emelec | – | León | | 2:1 (1:1) |
| Guayaquil |
Copa Libertadores 2014, Group 7 |
| 13.02.2014 | | Emelec | – | Bolívar | | 2:1 (1:1) |
| Guayaquil |
Copa Libertadores 2013, Round of 16 |
| 02.05.2013 | | Emelec | – | Fluminense | | 2:1 (1:1) |
| Guayaquil |
Copa Libertadores 2013, Group 4 |
| 02.04.2013 | | Emelec | – | Peñarol |  | 2:0 (0:0) |
| Guayaquil |
Copa Libertadores 2013, Group 4 |
| 05.03.2013 | | Emelec | – | Deportes Iquique | | 2:1 (0:0) |
| Guayaquil |
Copa Libertadores 2013, Group 4 |
| 12.02.2013 | | Emelec | – | Vélez Sársfield | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 2012, Group 2 |
| 12.04.2012 |  | Olimpia | – | Emelec | | 2:3 (1:0) |
| Asunción |
Copa Libertadores 2012, Group 2 |
| 04.04.2012 | | Emelec | – | Flamengo | | 3:2 (1:2) |
| Guayaquil |
Copa Libertadores 2012, Group 2 |
| 09.02.2012 | | Emelec | – | Olimpia | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 2011, Group 6 |
| 16.03.2011 | | Emelec | – | Jaguares | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 2011, Group 6 |
| 22.02.2011 | | Emelec | – | Jorge Wilstermann | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 2010, Preliminary Round |
| 10.02.2010 | | Emelec | – | Newell's Old Boys | | 2:1 (0:0) |
| Guayaquil |
Copa Libertadores 2007, Group 4 |
| 22.03.2007 | | Emelec | – | Nacional Montevideo | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 2003, Group 1 |
| 13.03.2003 | | Emelec | – | River Plate | | 3:1 (0:1) |
| Guayaquil |
Copa Libertadores 2001, 1/8 finals |
| 09.05.2001 | | Emelec | – | River Plate | | 2:0 (1:0) |
| Guayaquil |
Copa Libertadores 2001, Group 4 |
| 01.05.2001 | | Emelec | – | Sporting Cristal | | 3:1 (1:0) |
| Guayaquil |
Copa Libertadores 2001, Group 4 |
| 01.03.2001 | | Sporting Cristal | – | Emelec | | 0:1 (0:0) |
| Lima |
Copa Libertadores 1999, 1/8 finals |
| 21.04.1999 | | Estudiantes de Mérida | – | Emelec | | 0:1 (0:1) |
| Mérida |
Copa Libertadores 1999, Group 5 |
| 17.03.1999 | | Emelec | – | LDU | | 2:0 (0:0) |
| Guayaquil |
Copa Libertadores 1999, Group 5 |
| 09.03.1999 | | Emelec | – | Blooming | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 1999, Group 5 |
| 02.03.1999 | | Emelec | – | Jorge Wilstermann | | 3:2 (1:0) |
| Guayaquil |
Copa Libertadores 1997, Group 2 |
| 19.02.1997 | | Emelec | – | El Nacional | | 2:1 (1:0) |
| Guayaquil |
Copa Libertadores 1995, Quarterfinal |
| 26.07.1995 | | Emelec | – | Sporting Cristal | | 3:1 (2:1) |
| Guayaquil |
Copa Libertadores 1995, 1/8 finals |
| 26.04.1995 | | Emelec | – | Cerro Porteño | | 2:0 (0:0) |
| Guayaquil |
Copa Libertadores 1995, Group 4 |
| 22.03.1995 | | El Nacional | – | Emelec | | 0:2 (0:0) |
| Quito |
Copa Libertadores 1994, 1/8 finals |
| 27.04.1994 | | Emelec | – | Minervén | | 3:1 (3:1),
pen. 2:4 |
| Guayaquil |
Copa Libertadores 1994, Group 3 |
| 23.03.1994 | | Barcelona | – | Emelec | | 0:1 (0:0) |
| Guayaquil |
Copa Libertadores 1994, Group 3 |
| 18.03.1994 | | Emelec | – | Alianza Lima | | 3:0 (1:0) |
| Guayaquil |
Copa Libertadores 1994, Group 3 |
| 11.03.1994 | | Emelec | – | Universitario de Deportes | | 2:0 (0:0) |
| Guayaquil |
Copa Libertadores 1990, 1/8 finals |
| 15.08.1990 | | Emelec | – | Unión Huaral | | 2:0 (0:0) |
| Guayaquil |
Copa Libertadores 1990, Group 1 |
| 20.04.1990 | | Emelec | – | The Strongest | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 1990, Group 1 |
| 04.04.1990 | | Emelec | – | Barcelona | | 3:1 (3:0) |
| Guayaquil |
Copa Libertadores 1989, Group 3 |
| 12.02.1989 | | Emelec | – | Deportivo Quito | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 1980, First Round, Group 4 |
| 30.03.1980 | | Santa Fe | – | Emelec | | 1:2 (0:2) |
| Bogotá |
Copa Libertadores 1980, First Round, Group 4 |
| 09.03.1980 | | Emelec | – | Universidad Católica | | 1:0 (0:0) |
| Guayaquil |
Copa Libertadores 1973, First Round, Group 3 |
| 14.03.1973 | | Emelec | – | Colo-Colo | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 1973, First Round, Group 3 |
| 11.03.1973 | | Emelec | – | Unión Española | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 1973, First Round, Group 3 |
| 25.02.1973 | | Emelec | – | El Nacional | | 2:0 (0:0) |
| Guayaquil |
Copa Libertadores 1971, First Round, Group 5 |
| 07.03.1971 | | Emelec | – | Deportivo Cali | | 3:1 (2:1) |
| Guayaquil |
Copa Libertadores 1971, First Round, Group 5 |
| 28.02.1971 | | Barcelona | – | Emelec | | 0:1 (0:0) |
| Guayaquil |
Copa Libertadores 1968, Second round, group 2 |
| 24.03.1968 | | Emelec | – | Deportivo Portugués | | 2:0 (1:0) |
| Guayaquil |
Copa Libertadores 1968, First Round, Group 3 |
| 03.03.1968 | | El Nacional | – | Emelec | | 0:1 (0:0) |
| Quito |
Copa Libertadores 1968, First Round, Group 3 |
| 11.02.1968 | | Emelec | – | Universidad de Chile | | 2:1 (1:1) |
| Guayaquil |
Copa Libertadores 1967, First Round, Group 3 |
| 26.04.1967 | | Emelec | – | Colo-Colo | | 4:3 (2:2) |
| Guayaquil |
Copa Libertadores 1967, First Round, Group 3 |
| 22.03.1967 | | Universidad Católica | – | Emelec | | 1:2 (0:1) |
| Santiago |
Copa Libertadores 1967, First Round, Group 3 |
| 05.03.1967 | | Emelec | – | Cerro Porteño | | 2:1 (1:1) |
| Guayaquil |
Copa Libertadores 1967, First Round, Group 3 |
| 12.02.1967 | | Emelec | – | Barcelona | | 3:0 (2:0) |
| Guayaquil |
Copa Libertadores 1966, First Round, Group 3 |
| 23.03.1966 | | 9 de Octubre | – | Emelec | | 0:4 (0:1) |
| Guayaquil |
Copa Libertadores 1966, First Round, Group 3 |
| 24.02.1966 | | Emelec | – | Municipal | | 2:1 (1:0) |
| Guayaquil |
Copa Libertadores 1966, First Round, Group 3 |
| 19.02.1966 | | Emelec | – | Jorge Wilstermann | | 3:1 (1:0) |
| Guayaquil |
Copa Libertadores 1966, First Round, Group 3 |
| 30.01.1966 | | Emelec | – | 9 de Octubre | | 2:1 (1:0) |
| Guayaquil |
Copa Libertadores 1962, Group C |
| 21.02.1962 | | Emelec | – | Universidad Católica | | 7:2 (5:2) |
| Guayaquil |
Copa Libertadores 1962, Group C |
| 07.02.1962 | | Emelec | – | Los Millonarios | | 4:2 (0:1) |
| Guayaquil |
