Copa Libertadores 2014, Preliminary Round |
 | 05.02.2014 |  | Botafogo | – | Deportivo Quito |  | 4:0 (1:0) |
| Rio de Janeiro |
Copa Libertadores 2014, Preliminary Round |
| 29.01.2014 | | Deportivo Quito | – | Botafogo | | 1:0 (1:0) |
| Quito |
Copa Libertadores 2012, Round of 16 |
| 10.05.2012 |  | Universidad de Chile | – | Deportivo Quito | | 6:0 (0:0) |
| Santiago |
Copa Libertadores 2012, Round of 16 |
| 03.05.2012 | | Deportivo Quito | – | Universidad de Chile | | 4:1 (2:1) |
| Quito |
Copa Libertadores 2012, Group 7 |
| 17.04.2012 | | Deportivo Quito | – | Guadalajara |  | 5:0 (2:0) |
| Quito |
Copa Libertadores 2012, Group 7 |
| 10.04.2012 | | Deportivo Quito | – | Defensor Sporting |  | 2:0 (1:0) |
| Quito |
Copa Libertadores 2012, Group 7 |
| 22.03.2012 |  | Vélez Sársfield | – | Deportivo Quito | | 1:0 (0:0) |
| Buenos Aires |
Copa Libertadores 2012, Group 7 |
| 07.03.2012 | | Deportivo Quito | – | Vélez Sársfield | | 3:0 (1:0) |
| Quito |
Copa Libertadores 2012, Group 7 |
| 14.02.2012 | | Defensor Sporting | – | Deportivo Quito | | 2:0 (1:0) |
| Montevideo |
Copa Libertadores 2012, Group 7 |
| 07.02.2012 | | Guadalajara | – | Deportivo Quito | | 1:1 (0:1) |
| Guadalajara |
Copa Libertadores 2011, Preliminary Round |
| 01.02.2011 | | Deportivo Quito | – | Independiente | | 1:0 (0:0) |
| Quito |
Copa Libertadores 2011, Preliminary Round |
| 25.01.2011 | | Independiente | – | Deportivo Quito | | 2:0 (0:0) |
| Avellaneda |
Copa Libertadores 2010, Group 5 |
| 22.04.2010 | | Internacional | – | Deportivo Quito | | 3:0 (1:0) |
| Porto Alegre |
Copa Libertadores 2010, Group 5 |
| 13.04.2010 | | Deportivo Quito | – | Cerro | | 2:1 (1:1) |
| Quito |
Copa Libertadores 2010, Group 5 |
| 01.04.2010 | | Emelec | – | Deportivo Quito | | 0:1 (0:0) |
| Guayaquil |
Copa Libertadores 2010, Group 5 |
| 25.03.2010 | | Deportivo Quito | – | Emelec | | 1:0 (0:0) |
| Quito |
Copa Libertadores 2010, Group 5 |
| 11.03.2010 | | Deportivo Quito | – | Internacional | | 1:1 (1:1) |
| Quito |
Copa Libertadores 2010, Group 5 |
| 09.02.2010 | | Cerro | – | Deportivo Quito | | 2:0 (1:0) |
| Montevideo |
Copa Libertadores 2009, Group 5 |
| 22.04.2009 | | Cruzeiro | – | Deportivo Quito | | 2:0 (2:0) |
| Belo Horizonte |
Copa Libertadores 2009, Group 5 |
| 14.04.2009 | | Deportivo Quito | – | Universitario Sucre |  | 3:1 (2:1) |
| Quito |
Copa Libertadores 2009, Group 5 |
| 19.03.2009 | | Estudiantes La Plata | – | Deportivo Quito | | 4:0 (3:0) |
| La Plata |
Copa Libertadores 2009, Group 5 |
| 10.03.2009 | | Deportivo Quito | – | Estudiantes La Plata | | 1:0 (0:0) |
| Quito |
Copa Libertadores 2009, Group 5 |
| 25.02.2009 | | Deportivo Quito | – | Cruzeiro | | 1:1 (0:1) |
| Quito |
Copa Libertadores 2009, Group 5 |
| 12.02.2009 | | Universitario Sucre | – | Deportivo Quito | | 1:1 (0:0) |
| Sucre |
Copa Libertadores 1998, Group 1 |
| 27.03.1998 |  | América de Cali | – | Deportivo Quito | | 2:1 (0:0) |
| Santiago de Cali |
Copa Libertadores 1998, Group 1 |
| 24.03.1998 | | Atlético Bucaramanga | – | Deportivo Quito | | 2:0 (0:0) |
| Bucaramanga |
Copa Libertadores 1998, Group 1 |
| 18.03.1998 | | Deportivo Quito | – | Barcelona | | 1:1 (1:0) |
| Quito |
Copa Libertadores 1998, Group 1 |
| 10.03.1998 | | Deportivo Quito | – | América de Cali | | 0:4 (0:3) |
| Quito |
Copa Libertadores 1998, Group 1 |
| 03.03.1998 | | Deportivo Quito | – | Atlético Bucaramanga | | 1:0 (0:0) |
| Quito |
Copa Libertadores 1998, Group 1 |
| 25.02.1998 | | Barcelona | – | Deportivo Quito | | 0:0 |
| Guayaquil |
Copa Libertadores 1989, 1/8 finals |
| 12.04.1989 | | Cobreloa | – | Deportivo Quito | | 1:0 (0:0) |
| Calama |
Copa Libertadores 1989, 1/8 finals |
| 05.04.1989 | | Deportivo Quito | – | Cobreloa | | 0:0 |
| Quito |
Copa Libertadores 1989, Group 3 |
| 17.03.1989 | | Los Millonarios | – | Deportivo Quito | | 3:1 (2:0) |
| Bogotá |
Copa Libertadores 1989, Group 3 |
| 14.03.1989 | | Atlético Nacional | – | Deportivo Quito | | 2:1 (1:1) |
| Medellín |
Copa Libertadores 1989, Group 3 |
| 10.03.1989 | | Deportivo Quito | – | Emelec | | 1:0 (0:0) |
| Quito |
Copa Libertadores 1989, Group 3 |
| 03.03.1989 | | Deportivo Quito | – | Los Millonarios | | 0:0 |
| Quito |
Copa Libertadores 1989, Group 3 |
| 24.02.1989 | | Deportivo Quito | – | Atlético Nacional | | 1:1 (0:0) |
| Quito |
Copa Libertadores 1989, Group 3 |
| 12.02.1989 | | Emelec | – | Deportivo Quito | | 1:0 (1:0) |
| Guayaquil |
Copa Libertadores 1986, First Round, Group 4 |
| 29.07.1986 | | Deportivo Quito | – | Barcelona | | 0:0 |
| Quito |
Copa Libertadores 1986, First Round, Group 4 |
| 25.07.1986 | | Coritiba | – | Deportivo Quito | | 3:1 (0:1) |
| Curitiba |
Copa Libertadores 1986, First Round, Group 4 |
| 22.07.1986 | | Bangu | – | Deportivo Quito | | 3:3 (0:2) |
| Rio de Janeiro |
Copa Libertadores 1986, First Round, Group 4 |
| 06.05.1986 | | Deportivo Quito | – | Bangu | | 3:1 (2:0) |
| Quito |
Copa Libertadores 1986, First Round, Group 4 |
| 29.04.1986 | | Deportivo Quito | – | Coritiba | | 2:1 (1:0) |
| Quito |
Copa Libertadores 1986, First Round, Group 4 |
| 20.04.1986 | | Barcelona | – | Deportivo Quito | | 3:3 (1:2) |
| Guayaquil |
Copa Libertadores 1969, First Round, Group 4 |
| 16.03.1969 | | Nacional Montevideo | – | Deportivo Quito | | 4:0 (1:0) |
| Montevideo |
Copa Libertadores 1969, First Round, Group 4 |
| 12.03.1969 | | Peñarol | – | Deportivo Quito | | 5:2 (2:1) |
| Montevideo |
Copa Libertadores 1969, First Round, Group 4 |
| 09.03.1969 | | Barcelona | – | Deportivo Quito | | 0:0 |
| Guayaquil |
Copa Libertadores 1969, First Round, Group 4 |
| 02.03.1969 | | Deportivo Quito | – | Peñarol | | 1:1 (1:0) |
| Quito |
Copa Libertadores 1969, First Round, Group 4 |
| 26.02.1969 | | Deportivo Quito | – | Nacional Montevideo | | 0:0 |
| Quito |
Copa Libertadores 1969, First Round, Group 4 |
| 23.02.1969 | | Deportivo Quito | – | Barcelona | | 1:0 (1:0) |
| Quito |
Copa Libertadores 1965, Group 1 |
| 26.02.1965 | | Boca Juniors | – | Deportivo Quito | | 4:0 (1:0) |
| Buenos Aires |
Copa Libertadores 1965, Group 1 |
| 21.02.1965 | | The Strongest | – | Deportivo Quito | | 2:2 (1:1) |
| La Paz |
Copa Libertadores 1965, Group 1 |
| 07.02.1965 | | Deportivo Quito | – | Boca Juniors | | 1:2 (0:0) |
| Quito |
Copa Libertadores 1965, Group 1 |
| 31.01.1965 | | Deportivo Quito | – | The Strongest | | 0:1 (0:1) |
| Quito |
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