Copa Libertadores 2020, Group C |
 | 29.09.2020 |  | Atlético Paranaense | – | Jorge Wilstermann |  | 0:0 |
| Curitiba |
Copa Libertadores 2019, Group G |
| 03.04.2019 |  | Deportes Tolima | – | Jorge Wilstermann | | 2:2 (1:0) |
| Ibagué |
Copa Libertadores 2019, Group G |
| 05.03.2019 | | Jorge Wilstermann | – | Boca Juniors |  | 0:0 |
| Cochabamba |
Copa Libertadores 2018, Second qualifying stage |
| 08.02.2018 | | Jorge Wilstermann | – | Oriente Petrolero | | 2:2 (2:0) |
| Sucre |
Copa Libertadores 2017, Round of 16 |
| 09.08.2017 | | Atlético Mineiro | – | Jorge Wilstermann | | 0:0 |
| Belo Horizonte |
Copa Libertadores 2011, Group 6 |
| 07.04.2011 | | Jorge Wilstermann | – | Emelec |  | 0:0 |
| Cochabamba |
Copa Libertadores 2004, Group 7 |
| 24.03.2004 | | Jorge Wilstermann | – | Barcelona | | 2:2 (1:0) |
| Cochabamba |
Copa Libertadores 2004, Group 7 |
| 03.03.2004 | | Jorge Wilstermann | – | Guaraní Asunción |  | 0:0 |
| Cochabamba |
Copa Libertadores 1999, 1/8 finals |
| 14.04.1999 | | Jorge Wilstermann | – | Corinthians | | 1:1 (0:0) |
| Cochabamba |
Copa Libertadores 1999, Group 5 |
| 06.04.1999 | | Jorge Wilstermann | – | LDU | | 1:1 (1:0) |
| Cochabamba |
Copa Libertadores 1999, Group 5 |
| 24.02.1999 | | Blooming | – | Jorge Wilstermann | | 0:0 |
| Santa Cruz de la Sierra |
Copa Libertadores 1995, Group 5 |
| 08.03.1995 | | Jorge Wilstermann | – | Bolívar | | 1:1 (1:0) |
| Cochabamba |
Copa Libertadores 1995, Group 5 |
| 21.02.1995 | | Jorge Wilstermann | – | Sporting Cristal |  | 2:2 (0:1) |
| Cochabamba |
Copa Libertadores 1982, First Round, Group 1 |
| 30.09.1982 | | The Strongest | – | Jorge Wilstermann | | 1:1 (0:0) |
| La Paz |
Copa Libertadores 1982, First Round, Group 1 |
| 17.09.1982 | | Boca Juniors | – | Jorge Wilstermann | | 2:2 (1:0) |
| Buenos Aires |
Copa Libertadores 1981, Semifinal group 1 |
| 27.10.1981 | | Jorge Wilstermann | – | Deportivo Cali | | 1:1 (1:0) |
| Cochabamba |
Copa Libertadores 1975, First Round, Group 2 |
| 26.03.1975 | | Jorge Wilstermann | – | The Strongest | | 1:1 (0:0) |
| Cochabamba |
Copa Libertadores 1975, First Round, Group 2 |
| 12.03.1975 | | Jorge Wilstermann | – | Unión Española |  | 1:1 (1:0) |
| Cochabamba |
Copa Libertadores 1975, First Round, Group 2 |
| 05.03.1975 | | Jorge Wilstermann | – | Huachipato | | 0:0 |
| Cochabamba |
Copa Libertadores 1973, First Round, Group 1 |
| 19.03.1973 | | River Plate | – | Jorge Wilstermann | | 2:2 (1:1) |
| Buenos Aires |
Copa Libertadores 1968, First Round, Group 2 |
| 28.01.1968 | | Jorge Wilstermann | – | Universitario de Deportes | | 0:0 |
| Cochabamba |
Copa Libertadores 1966, First Round, Group 3 |
| 13.02.1966 | | Jorge Wilstermann | – | Nacional Montevideo |  | 0:0 |
| Cochabamba |
Copa Libertadores 1966, First Round, Group 3 |
| 30.01.1966 | | Municipal | – | Jorge Wilstermann | | 1:1 (1:1) |
| La Paz |
Copa Libertadores 1960, Quarterfinal |
| 30.04.1960 | | Jorge Wilstermann | – | Peñarol | | 1:1 (0:1) |
| La Paz |
