Copa Libertadores 2022, Group E |
 | 04.05.2022 | | Deportivo Cali | – | Corinthians | | 0:0 |
| Santiago de Cali |
Copa Libertadores 2022, Group E |
| 28.04.2022 | | Always Ready | – | Deportivo Cali | | 2:2 (2:1) |
| La Paz |
Copa Libertadores 2016, Group 3 |
| 14.04.2016 | | Deportivo Cali | – | Bolívar | | 1:1 (1:0) |
| Santiago de Cali |
Copa Libertadores 2016, Group 3 |
| 17.03.2016 | | Deportivo Cali | – | Racing Club | | 2:2 (2:0) |
| Santiago de Cali |
Copa Libertadores 2016, Group 3 |
| 24.02.2016 | | Deportivo Cali | – | Boca Juniors | | 0:0 |
| Santiago de Cali |
Copa Libertadores 2014, Group 3 |
| 26.03.2014 | | Deportivo Cali | – | O'Higgins | | 1:1 (0:0) |
| Santiago de Cali |
Copa Libertadores 2006, Group 4 |
| 11.04.2006 | | Deportivo Cali | – | Sinergia Deportiva | | 2:2 (1:1) |
| Santiago de Cali |
Copa Libertadores 2003, 1/8 finals |
| 13.05.2003 | | Deportivo Cali | – | Cruz Azul | | 0:0,
pen. 2:3 |
| Santiago de Cali |
Copa Libertadores 2003, 1/8 finals |
| 06.05.2003 | | Cruz Azul | – | Deportivo Cali | | 0:0 |
| Ciudad de México |
Copa Libertadores 1999, Quarterfinal |
| 12.05.1999 | | Bella Vista | – | Deportivo Cali | | 1:1 (0:0) |
| Maldonado |
Copa Libertadores 1997, Group 5 |
| 15.04.1997 | | Nacional Montevideo | – | Deportivo Cali | | 1:1 (1:1) |
| Montevideo |
Copa Libertadores 1997, Group 5 |
| 19.03.1997 | | Los Millonarios | – | Deportivo Cali | | 2:2 (2:0) |
| Bogotá |
Copa Libertadores 1987, First Round, Group 2 |
| 08.07.1987 | | América de Cali | – | Deportivo Cali | | 0:0 aet,
pen. 4:2 * |
| Santiago de Cali |
Copa Libertadores 1986, First Round, Group 2 |
| 22.04.1986 | | Cobresal | – | Deportivo Cali | | 1:1 (1:1) |
| El Salvador |
Copa Libertadores 1986, First Round, Group 2 |
| 21.03.1986 | | Deportivo Cali | – | Cobresal | | 1:1 (1:1) |
| Santiago de Cali |
Copa Libertadores 1986, First Round, Group 2 |
| 12.03.1986 | | América de Cali | – | Deportivo Cali | | 0:0 |
| Santiago de Cali |
Copa Libertadores 1981, Semifinal group 1 |
| 27.10.1981 | | Jorge Wilstermann | – | Deportivo Cali | | 1:1 (1:0) |
| Cochabamba |
Copa Libertadores 1979, First Round, Group 1 |
| 14.03.1979 | | Los Millonarios | – | Deportivo Cali | | 1:1 (0:1) |
| Bogotá |
Copa Libertadores 1978, Final |
| 23.11.1978 | | Deportivo Cali | – | Boca Juniors | | 0:0 |
| Santiago de Cali |
Copa Libertadores 1978, Semifinal group 2 |
| 17.09.1978 | | Deportivo Cali | – | Cerro Porteño | | 1:1 (0:0) |
| Santiago de Cali |
Copa Libertadores 1978, First Round, Group 4 |
| 09.07.1978 | | Deportivo Cali | – | Junior | | 0:0 |
| Santiago de Cali |
Copa Libertadores 1978, First Round, Group 4 |
| 12.04.1978 | | Junior | – | Deportivo Cali | | 0:0 |
| Barranquilla |
Copa Libertadores 1977, Semifinal group 1 |
| 16.08.1977 | | Boca Juniors | – | Deportivo Cali | | 1:1 (0:0) |
| Buenos Aires |
Copa Libertadores 1977, Semifinal group 1 |
| 03.08.1977 | | Deportivo Cali | – | Boca Juniors | | 1:1 (1:1) |
| Santiago de Cali |
Copa Libertadores 1977, Semifinal group 1 |
| 27.07.1977 | | Deportivo Cali | – | Libertad | | 0:0 |
| Santiago de Cali |
Copa Libertadores 1975, First Round, Group 3 |
| 06.04.1975 | | Vasco da Gama | – | Deportivo Cali | | 0:0 |
| Rio de Janeiro |
Copa Libertadores 1975, First Round, Group 3 |
| 23.02.1975 | | Deportivo Cali | – | Atlético Nacional | | 0:0 |
| Santiago de Cali |
Copa Libertadores 1973, First Round, Group 4 |
| 21.03.1973 | | Deportivo Cali | – | Los Millonarios | | 0:0 |
| Santiago de Cali |
Copa Libertadores 1970, First Round, Group 3 |
| 24.03.1970 | | Guaraní Asunción | – | Deportivo Cali | | 1:1 (1:0) |
| Asunción |
Copa Libertadores 1970, First Round, Group 3 |
| 08.03.1970 | | Deportivo Cali | – | Guaraní Asunción | | 0:0 |
| Santiago de Cali |
Copa Libertadores 1969, Second round, group 2 |
| 16.04.1969 | | Santiago Wanderers | – | Deportivo Cali | | 3:3 (2:0) |
| Viña del Mar |
Copa Libertadores 1969, First Round, Group 1 |
| 26.02.1969 | | Canarias | – | Deportivo Cali | | 1:1 (0:0) |
| Caracas |
Copa Libertadores 1969, First Round, Group 1 |
| 23.02.1969 | | Unión Magdalena | – | Deportivo Cali | | 2:2 (0:0) |
| Santa Marta |
Copa Libertadores 1968, First Round, Group 1 |
| 22.02.1968 | | Independiente Avellaneda | – | Deportivo Cali | | 1:1 (1:0) |
| Avellaneda |
Ukraine
Azerbaijan
Armenia
Kazakhstan
Moldova
Austria
England
Belgium
Bulgaria
Hungary
Germany
Netherlands
Georgia
Iceland
Spain
Italy
Lithuania
Norway
Poland
Portugal
Serbia
Slovenia
France
Croatia
Montenegro
Czech
Sweden
Scotland
Estonia
Brazil
Canada
Australia
