Copa Libertadores 2018, Second qualifying stage |
 | 08.02.2018 |  | Jorge Wilstermann | – | Oriente Petrolero | | 2:2 (2:0) |
| Sucre |
Copa Libertadores 2003, Group 6 |
| 08.04.2003 | | Oriente Petrolero | – | Universitario de Deportes |  | 2:2 (0:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 2001, Group 8 |
| 02.05.2001 | | Oriente Petrolero | – | Cobreloa |  | 2:2 (0:1) |
| Santa Cruz de la Sierra |
Copa Libertadores 1998, Group 4 |
| 18.03.1998 | | Oriente Petrolero | – | Bolívar | | 1:1 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1998, Group 4 |
| 03.03.1998 | | Oriente Petrolero | – | Peñarol |  | 0:0 |
| Santa Cruz de la Sierra |
Copa Libertadores 1997, Group 1 |
| 18.03.1997 |  | Guaraní Asunción | – | Oriente Petrolero | | 0:0 |
| Asunción |
Copa Libertadores 1997, Group 1 |
| 12.03.1997 | | Bolívar | – | Oriente Petrolero | | 3:3 (1:2) |
| La Paz |
Copa Libertadores 1991, 1/8 finals |
| 19.04.1991 | | Oriente Petrolero | – | Cerro Porteño | | 1:1 (0:1) |
| Santa Cruz de la Sierra |
Copa Libertadores 1991, Group 1 |
| 05.04.1991 |  | Boca Juniors | – | Oriente Petrolero | | 0:0 |
| Buenos Aires |
Copa Libertadores 1991, Group 1 |
| 08.03.1991 | | Oriente Petrolero | – | River Plate | | 1:1 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1990, Group 1 |
| 14.04.1990 | | Oriente Petrolero | – | Barcelona |  | 1:1 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1990, Group 1 |
| 30.03.1990 | | Emelec | – | Oriente Petrolero | | 2:2 (1:2) |
| Guayaquil |
Copa Libertadores 1988, Quarterfinal |
| 21.09.1988 | | Oriente Petrolero | – | América de Cali |  | 1:1 (1:1) |
| Santa Cruz de la Sierra |
Copa Libertadores 1988, 1/8 finals |
| 14.09.1988 | | Colo-Colo | – | Oriente Petrolero | | 0:0 |
| Santiago |
Copa Libertadores 1988, Group 4 |
| 26.07.1988 | | Oriente Petrolero | – | Cerro Porteño | | 2:2 |
| Santa Cruz de la Sierra |
Copa Libertadores 1987, First Round, Group 2 |
| 22.05.1987 | | Oriente Petrolero | – | América de Cali | | 1:1 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1985, First Round, Group 2 |
| 17.03.1985 |  | Deportivo Táchira | – | Oriente Petrolero | | 1:1 (1:1) |
| San Cristóbal |
Copa Libertadores 1985, First Round, Group 2 |
| 10.03.1985 | | Blooming | – | Oriente Petrolero | | 1:1 (0:1) * |
| Santa Cruz de la Sierra |
Copa Libertadores 1980, First Round, Group 2 |
| 30.04.1980 | | Defensor Sporting | – | Oriente Petrolero | | 1:1 (1:0) |
| Montevideo |
Copa Libertadores 1977, First Round, Group 2 |
| 15.05.1977 | | Oriente Petrolero | – | Bolívar | | 0:0 |
| Santa Cruz de la Sierra |
Copa Libertadores 1972, First Round, Group 2 |
| 26.03.1972 | | Barcelona | – | Oriente Petrolero | | 1:1 (1:1) |
| Guayaquil |
Copa Libertadores 1972, First Round, Group 2 |
| 15.03.1972 | | Oriente Petrolero | – | Barcelona | | 0:0 |
| Santa Cruz de la Sierra |
