Copa América 2021, Group A |
 | 18.06.2021 |  | Chile | – | Bolivia |  | 1:0 (1:0) * |
| Cuiabá |
Copa América 2019, Group C |
| 21.06.2019 |  | Ecuador | – | Chile | | 1:2 (1:1) |
| Salvador |
Copa América 2019, Group C |
| 17.06.2019 |  | Japan | – | Chile | | 0:4 (0:1) |
| São Paulo |
Copa América Centenario 2016 (commemorative), Semifinal |
| 22.06.2016 |  | Colombia | – | Chile | | 0:2 (0:2) |
| Chicago |
Copa América Centenario 2016 (commemorative), Quarterfinal |
| 18.06.2016 |  | Mexico | – | Chile | | 0:7 (0:2) |
| Santa Clara |
Copa América Centenario 2016 (commemorative), Group D |
| 14.06.2016 | | Chile | – | Panama |  | 4:2 (2:1) |
| Philadelphia |
Copa América Centenario 2016 (commemorative), Group D |
| 10.06.2016 | | Chile | – | Bolivia | | 2:1 (0:0) |
| Foxborough |
Copa América 2015, Semifinal |
| 29.06.2015 | | Chile | – | Peru |  | 2:1 (1:0) |
| Santiago |
Copa América 2015, Quarterfinal |
| 24.06.2015 | | Chile | – | Uruguay |  | 1:0 (0:0) |
| Santiago |
Copa América 2015, Group A |
| 19.06.2015 | | Chile | – | Bolivia | | 5:0 (2:0) |
| Santiago |
Copa América 2015, Group A |
| 11.06.2015 | | Chile | – | Ecuador | | 2:0 (0:0) |
| Santiago |
Copa América 2011, Group C |
| 12.07.2011 | | Chile | – | Peru | | 1:0 (0:0) |
| Mendoza |
Copa América 2011, Group C |
| 04.07.2011 | | Chile | – | Mexico U22 | | 2:1 (0:1) |
| San Juan |
Copa América 2007, Group B |
| 27.06.2007 | | Ecuador | – | Chile | | 2:3 (2:1) |
| Puerto Ordaz |
Copa América 2001, Group A |
| 14.07.2001 | | Chile | – | Venezuela |  | 1:0 (0:0) |
| Barranquilla |
Copa América 2001, Group A |
| 11.07.2001 | | Ecuador | – | Chile | | 1:4 (0:1) |
| Barranquilla |
Copa América 1999, Quarterfinal |
| 11.07.1999 | | Colombia | – | Chile | | 2:3 (2:1) |
| Luque |
Copa América 1999, Group B |
| 03.07.1999 | | Chile | – | Venezuela | | 3:0 (2:0) |
| Ciudad del Este |
Copa América 1993, Group B |
| 21.06.1993 | | Chile | – | Brazil |  | 3:2 (1:1) |
| Cuenca |
Copa América 1991, Group A |
| 14.07.1991 | | Chile | – | Paraguay |  | 4:0 (2:0) |
| Santiago |
Copa América 1991, Group A |
| 08.07.1991 | | Chile | – | Peru | | 4:2 (1:0) |
| Concepción |
Copa América 1991, Group A |
| 06.07.1991 | | Chile | – | Venezuela | | 2:0 (2:0) |
| Santiago |
Copa América 1989, Group B |
| 10.07.1989 | | Chile | – | Ecuador | | 2:1 (1:0) |
| Goiânia |
Copa América 1989, Group B |
| 08.07.1989 | | Chile | – | Bolivia | | 5:0 (2:0) |
| Goiânia |
Copa América 1987, Semifinal |
| 08.07.1987 | | Chile | – | Colombia | | 2:1 aet
(0:0) |
| Córdoba |
Copa América 1987, Group B |
| 03.07.1987 | | Chile | – | Brazil | | 4:0 (2:0) |
| Córdoba |
Copa América 1987, Group B |
| 30.06.1987 | | Chile | – | Venezuela | | 3:1 (1:1) |
| Córdoba |
Copa América 1983, Group 1 |
| 11.09.1983 | | Chile | – | Uruguay | | 2:0 (1:0) |
| Santiago |
Copa América 1983, Group 1 |
| 08.09.1983 | | Chile | – | Venezuela | | 5:0 (3:0) |
| Santiago |
Copa América 1979, Final |
| 05.12.1979 | | Chile | – | Paraguay | | 1:0 (1:0) |
| Santiago |
Copa América 1979, Semifinal |
| 17.10.1979 | | Peru | – | Chile | | 1:2 (0:1) |
| Lima |
Copa América 1979, Group 1 |
| 05.09.1979 | | Chile | – | Colombia | | 2:0 (1:0) |
| Santiago |
Copa América 1979, Group 1 |
| 29.08.1979 | | Chile | – | Venezuela | | 7:0 (2:0) |
| Santiago |
Copa América 1975, Group 2 |
| 13.08.1975 | | Chile | – | Bolivia | | 4:0 (1:0) |
| Santiago |
South American Championship 1967, Final tournament, Final Round |
| 22.01.1967 | | Chile | – | Paraguay | | 4:2 (2:2) |
| Montevideo |
South American Championship 1967, Final tournament, Final Round |
| 18.01.1967 | | Chile | – | Venezuela | | 2:0 (2:0) |
| Montevideo |
South American Championship 1967, Qualifying tournament, Qualifying round |
| 30.11.1966 | | Chile | – | Colombia | | 5:2 (3:0) |
| Santiago |
South American Championship 1959, Final Round |
| 02.04.1959 | | Chile | – | Uruguay | | 1:0 (0:0) |
| Buenos Aires |
South American Championship 1959, Final Round |
| 26.03.1959 | | Chile | – | Bolivia | | 5:2 (3:1) |
| Buenos Aires |
South American Championship 1957, Final Round |
| 21.03.1957 | | Chile | – | Colombia | | 3:2 (1:0) |
| Lima |
South American Championship 1956 (unofficial), Final Round |
| 12.02.1956 | | Chile | – | Paraguay | | 2:0 (0:0) |
| Montevideo |
South American Championship 1956 (unofficial), Final Round |
| 09.02.1956 | | Chile | – | Peru | | 4:3 (2:1) |
| Montevideo |
South American Championship 1956 (unofficial), Final Round |
| 24.01.1956 | | Chile | – | Brazil | | 4:1 (1:1) |
| Montevideo |
South American Championship 1955, Final Round |
| 20.03.1955 | | Chile | – | Paraguay | | 5:0 (1:0) |
| Santiago |
South American Championship 1955, Final Round |
| 06.03.1955 | | Chile | – | Peru | | 5:4 (2:1) |
| Santiago |
South American Championship 1955, Final Round |
| 27.02.1955 | | Chile | – | Ecuador | | 7:1 (4:0) |
| Santiago |
South American Championship 1953, Final Round |
| 19.03.1953 | | Chile | – | Ecuador | | 3:0 (1:0) |
| Lima |
South American Championship 1953, Final Round |
| 01.03.1953 | | Chile | – | Uruguay | | 3:2 (1:0) |
| Lima |
South American Championship 1949, Final Round |
| 08.05.1949 | | Chile | – | Uruguay | | 3:1 (0:1) |
| Belo Horizonte |
South American Championship 1949, Final Round |
| 17.04.1949 | | Chile | – | Ecuador | | 1:0 (1:0) |
| Rio de Janeiro |
South American Championship 1947, Final Round |
| 31.12.1947 | | Chile | – | Bolivia | | 4:3 (2:0) |
| Guayaquil |
South American Championship 1947, Final Round |
| 29.12.1947 | | Chile | – | Colombia | | 4:1 (1:0) |
| Guayaquil |
South American Championship 1947, Final Round |
| 11.12.1947 | | Ecuador | – | Chile | | 0:3 (0:0) |
| Guayaquil |
South American Championship 1947, Final Round |
| 09.12.1947 | | Chile | – | Peru | | 2:1 (1:0) |
| Guayaquil |
South American Championship 1946 (unofficial), Final Round |
| 08.02.1946 | | Chile | – | Bolivia | | 4:1 (2:0) |
| Buenos Aires |
South American Championship 1946 (unofficial), Final Round |
| 19.01.1946 | | Chile | – | Paraguay | | 2:1 (0:1) |
| Buenos Aires |
South American Championship 1945 (unofficial), Final Round |
| 18.02.1945 | | Chile | – | Uruguay | | 1:0 (1:0) |
| Santiago |
South American Championship 1945 (unofficial), Final Round |
| 31.01.1945 | | Chile | – | Colombia | | 2:0 (1:0) |
| Santiago |
South American Championship 1945 (unofficial), Final Round |
| 24.01.1945 | | Chile | – | Bolivia | | 5:0 (3:0) |
| Santiago |
South American Championship 1945 (unofficial), Final Round |
| 14.01.1945 | | Chile | – | Ecuador | | 6:3 (3:2) |
| Santiago |
South American Championship 1942, Final Round |
| 05.02.1942 | | Chile | – | Ecuador | | 2:1 (2:1) |
| Montevideo |
South American Championship 1941 (unofficial), Final Round |
| 09.02.1941 | | Chile | – | Peru | | 1:0 (1:0) |
| Santiago |
South American Championship 1941 (unofficial), Final Round |
| 02.02.1941 | | Chile | – | Ecuador | | 5:0 (4:0) |
| Santiago |
South American Championship 1939, Final Round |
| 05.02.1939 | | Chile | – | Ecuador | | 4:1 (3:1) |
| Lima |
South American Championship 1937, Final Round |
| 10.01.1937 | | Chile | – | Uruguay | | 3:0 (1:0) |
| Buenos Aires |
South American Championship 1926, Final Round |
| 03.11.1926 | | Chile | – | Paraguay | | 5:1 (2:0) |
| Santiago |
South American Championship 1926, Final Round |
| 12.10.1926 | | Chile | – | Bolivia | | 7:1 (4:1) |
| Santiago |
