Copa Libertadores 2018, First qualifying stage |
 | 22.01.2018 |  | Oriente Petrolero | – | Universitario de Deportes |  | 2:0 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 2014, Preliminary Round |
| 28.01.2014 | | Oriente Petrolero | – | Nacional Montevideo |  | 1:0 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 2011, Group 2 |
| 14.04.2011 | | Oriente Petrolero | – | Grêmio |  | 3:0 (0:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 2011, Group 2 |
| 24.03.2011 | | Oriente Petrolero | – | León | | 2:0 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 2002, Group 2 |
| 02.04.2002 | | Oriente Petrolero | – | 12 de Octubre |  | 1:0 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 2002, Group 2 |
| 13.02.2002 | | Oriente Petrolero | – | Cienciano | | 3:1 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1998, Group 4 |
| 10.03.1998 | | Oriente Petrolero | – | Nacional Montevideo | | 2:1 (0:1) |
| Santa Cruz de la Sierra |
Copa Libertadores 1997, Group 1 |
| 04.03.1997 | | Oriente Petrolero | – | Cerro Porteño | | 1:0 (0:0) |
| Cochabamba |
Copa Libertadores 1997, Group 1 |
| 25.02.1997 | | Oriente Petrolero | – | Guaraní Asunción | | 4:1 (0:1) |
| Cochabamba |
Copa Libertadores 1991, Group 1 |
| 20.03.1991 | | Oriente Petrolero | – | Bolívar | | 2:1 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1991, Group 1 |
| 15.03.1991 | | Oriente Petrolero | – | Boca Juniors |  | 1:0 (0:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1990, Group 1 |
| 16.05.1990 | | Oriente Petrolero | – | Barcelona |  | 3:2 (2:2),
pen. 4:5 * |
| Santa Cruz de la Sierra |
Copa Libertadores 1990, Group 1 |
| 04.04.1990 | | Oriente Petrolero | – | The Strongest | | 1:0 (0:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1990, Group 1 |
| 23.03.1990 | | Oriente Petrolero | – | Emelec | | 1:0 (0:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1988, 1/8 finals |
| 08.09.1988 | | Oriente Petrolero | – | Colo-Colo |  | 2:1 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1988, Group 4 |
| 19.08.1988 | | Olimpia | – | Oriente Petrolero | | 1:2 (1:0) |
| Asunción |
Copa Libertadores 1988, Group 4 |
| 19.07.1988 | | Oriente Petrolero | – | Olimpia | | 1:0 (0:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1988, Group 4 |
| 05.07.1988 | | Bolívar | – | Oriente Petrolero | | 1:2 (0:0) |
| La Paz |
Copa Libertadores 1987, First Round, Group 2 |
| 29.05.1987 | | Oriente Petrolero | – | The Strongest | | 2:1 (1:0) * |
| Santa Cruz de la Sierra |
Copa Libertadores 1985, First Round, Group 2 |
| 11.04.1985 | | Oriente Petrolero | – | Deportivo Táchira |  | 3:2 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1985, First Round, Group 2 |
| 04.04.1985 | | Oriente Petrolero | – | Deportivo Italia | | 3:1 (1:1) |
| Santa Cruz de la Sierra |
Copa Libertadores 1985, First Round, Group 2 |
| 21.03.1985 | | Deportivo Italia | – | Oriente Petrolero | | 0:3 (0:0) |
| Caracas |
Copa Libertadores 1980, First Round, Group 2 |
| 09.04.1980 | | Oriente Petrolero | – | The Strongest | | 1:0 (0:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1978, First Round, Group 2 |
| 22.07.1978 | | Oriente Petrolero | – | The Strongest | | 4:1 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1977, First Round, Group 2 |
| 08.05.1977 | | Oriente Petrolero | – | Deportivo Cali |  | 1:0 (0:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1977, First Round, Group 2 |
| 04.05.1977 | | Oriente Petrolero | – | Atlético Nacional | | 4:0 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1973, First Round, Group 1 |
| 11.03.1973 | | Oriente Petrolero | – | Jorge Wilstermann | | 3:1 (1:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1972, First Round, Group 2 |
| 12.03.1972 | | Oriente Petrolero | – | América Quito | | 4:2 (2:1) |
| Santa Cruz de la Sierra |
Copa Libertadores 1972, First Round, Group 2 |
| 27.02.1972 | | Oriente Petrolero | – | Chaco Petrolero | | 5:0 (2:0) |
| Santa Cruz de la Sierra |
