Copa Libertadores 2022, Group E |
 | 19.05.2022 |  | Deportivo Cali | – | Always Ready |  | 3:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 2022, Group E |
| 05.04.2022 | | Deportivo Cali | – | Boca Juniors |  | 2:0 (0:0) |
| Santiago de Cali |
Copa Libertadores 2014, Group 3 |
| 13.03.2014 | | Deportivo Cali | – | Lanús | | 2:1 (0:1) |
| Santiago de Cali |
Copa Libertadores 2014, Group 3 |
| 12.02.2014 | | Deportivo Cali | – | Cerro Porteño |  | 1:0 (0:0) |
| Santiago de Cali |
Copa Libertadores 2004, 1/8 finals |
| 05.05.2004 | | Deportivo Cali | – | Cruzeiro |  | 1:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 2004, Group 8 |
| 21.04.2004 | | Deportivo Cali | – | Colo-Colo |  | 3:1 (1:0) |
| Santiago de Cali |
Copa Libertadores 2004, Group 8 |
| 02.03.2004 | | Deportivo Cali | – | Bolívar | | 3:1 (1:0) |
| Santiago de Cali |
Copa Libertadores 2004, Group 8 |
| 03.02.2004 | | Colo-Colo | – | Deportivo Cali | | 2:3 (1:2) |
| Santiago |
Copa Libertadores 2003, Group 1 |
| 01.04.2003 | | Deportivo Cali | – | Emelec |  | 1:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 2003, Group 1 |
| 11.03.2003 | | Deportivo Cali | – | Libertad | | 1:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 2003, Group 1 |
| 25.02.2003 | | Emelec | – | Deportivo Cali | | 0:4 (0:1) |
| Guayaquil |
Copa Libertadores 2003, Group 1 |
| 19.02.2003 | | Deportivo Cali | – | River Plate | | 2:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 2001, Group 8 |
| 02.05.2001 | | Deportivo Cali | – | Boca Juniors | | 3:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 2001, Group 8 |
| 20.04.2001 | | Deportivo Cali | – | Oriente Petrolero | | 4:1 (3:0) |
| Santiago de Cali |
Copa Libertadores 2001, Group 8 |
| 02.03.2001 | | Oriente Petrolero | – | Deportivo Cali | | 1:3 (1:2) |
| Santa Cruz de la Sierra |
Copa Libertadores 1999, Final |
| 02.06.1999 | | Deportivo Cali | – | Palmeiras | | 1:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 1999, Semifinal |
| 19.05.1999 | | Deportivo Cali | – | Cerro Porteño | | 4:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 1999, Quarterfinal |
| 05.05.1999 | | Deportivo Cali | – | Bella Vista |  | 2:1 (1:1) |
| Santiago de Cali |
Copa Libertadores 1999, 1/8 finals |
| 14.04.1999 | | Deportivo Cali | – | Colo-Colo | | 2:0 (2:0) |
| Santiago de Cali |
Copa Libertadores 1999, Group 2 |
| 11.03.1999 | | Deportivo Cali | – | Vélez Sársfield | | 1:0 (0:0) |
| Santiago de Cali |
Copa Libertadores 1999, Group 2 |
| 04.03.1999 | | Deportivo Cali | – | River Plate | | 1:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 1999, Group 2 |
| 24.02.1999 | | Deportivo Cali | – | Once Caldas | | 1:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 1997, Group 5 |
| 11.03.1997 | | Deportivo Cali | – | Peñarol | | 2:0 (0:0) |
| Santiago de Cali |
Copa Libertadores 1987, First Round, Group 2 |
| 09.06.1987 | | Deportivo Cali | – | The Strongest | | 4:0 (2:0) |
| Santiago de Cali |
Copa Libertadores 1987, First Round, Group 2 |
| 02.06.1987 | | Deportivo Cali | – | Oriente Petrolero | | 5:1 (3:0) |
| Santiago de Cali |
Copa Libertadores 1987, First Round, Group 2 |
| 26.05.1987 | | Deportivo Cali | – | América de Cali | | 2:1 (2:0) |
| Santiago de Cali |
Copa Libertadores 1987, First Round, Group 2 |
| 15.05.1987 | | Oriente Petrolero | – | Deportivo Cali | | 0:1 (0:0) |
| Santa Cruz de la Sierra |
Copa Libertadores 1986, First Round, Group 2 |
| 15.04.1986 | | Universidad Católica | – | Deportivo Cali | | 1:3 (1:2) |
| Santiago |
Copa Libertadores 1986, First Round, Group 2 |
| 04.04.1986 | | Deportivo Cali | – | Universidad Católica | | 3:1 (1:0) |
| Santiago de Cali |
Copa Libertadores 1981, Semifinal group 1 |
| 16.10.1981 | | Deportivo Cali | – | Jorge Wilstermann | | 1:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 1981, First Round, Group 1 |
| 22.04.1981 | | River Plate | – | Deportivo Cali | | 1:2 (1:1) |
| Buenos Aires |
Copa Libertadores 1981, First Round, Group 1 |
| 09.04.1981 | | Deportivo Cali | – | Junior | | 4:1 (2:1) |
| Santiago de Cali |
Copa Libertadores 1981, First Round, Group 1 |
| 03.04.1981 | | Deportivo Cali | – | River Plate | | 2:1 (1:0) |
| Santiago de Cali |
Copa Libertadores 1981, First Round, Group 1 |
| 31.03.1981 | | Deportivo Cali | – | Rosario Central | | 1:0 (0:0) |
| Santiago de Cali |
Copa Libertadores 1979, First Round, Group 1 |
| 04.04.1979 | | Deportivo Cali | – | Los Millonarios | | 2:0 (0:0) |
| Santiago de Cali |
Copa Libertadores 1979, First Round, Group 1 |
| 23.03.1979 | | Deportivo Cali | – | Independiente Avellaneda | | 1:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 1979, First Round, Group 1 |
| 20.03.1979 | | Deportivo Cali | – | Quilmes | | 3:2 (1:1) |
| Santiago de Cali |
Copa Libertadores 1978, Semifinal group 2 |
| 18.10.1978 | | Cerro Porteño | – | Deportivo Cali | | 0:4 (0:1) |
| Asunción |
Copa Libertadores 1978, Semifinal group 2 |
| 14.10.1978 |  | Alianza Lima | – | Deportivo Cali | | 1:4 (0:1) |
| Lima |
Copa Libertadores 1978, Semifinal group 2 |
| 21.09.1978 | | Deportivo Cali | – | Alianza Lima | | 3:2 (2:2) |
| Santiago de Cali |
Copa Libertadores 1978, First Round, Group 4 |
| 18.07.1978 | | Peñarol | – | Deportivo Cali | | 0:2 (0:1) |
| Montevideo |
Copa Libertadores 1978, First Round, Group 4 |
| 17.05.1978 | | Deportivo Cali | – | Danubio | | 2:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 1978, First Round, Group 4 |
| 14.05.1978 | | Deportivo Cali | – | Peñarol | | 1:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 1977, First Round, Group 2 |
| 22.05.1977 | | Deportivo Cali | – | Oriente Petrolero | | 3:0 (2:0) |
| Santiago de Cali |
Copa Libertadores 1977, First Round, Group 2 |
| 19.05.1977 | | Deportivo Cali | – | Bolívar | | 3:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 1977, First Round, Group 2 |
| 15.05.1977 | | Deportivo Cali | – | Atlético Nacional | | 3:1 (1:1) |
| Santiago de Cali |
Copa Libertadores 1977, First Round, Group 2 |
| 27.04.1977 | | Atlético Nacional | – | Deportivo Cali | | 0:3 (0:2) |
| Medellín |
Copa Libertadores 1975, First Round, Group 3 |
| 13.03.1975 | | Deportivo Cali | – | Vasco da Gama | | 2:1 (1:1) |
| Santiago de Cali |
Copa Libertadores 1975, First Round, Group 3 |
| 09.03.1975 | | Deportivo Cali | – | Cruzeiro | | 1:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 1971, First Round, Group 5 |
| 28.03.1971 | | Deportivo Cali | – | Junior | | 2:0 (1:0) |
| Santiago de Cali |
Copa Libertadores 1971, First Round, Group 5 |
| 21.03.1971 | | Deportivo Cali | – | Barcelona | | 3:1 (0:0) |
| Santiago de Cali |
Copa Libertadores 1971, First Round, Group 5 |
| 18.03.1971 | | Deportivo Cali | – | Emelec | | 1:0 (0:0) |
| Santiago de Cali |
Copa Libertadores 1970, First Round, Group 3 |
| 18.03.1970 | | Rangers | – | Deportivo Cali | | 0:2 (0:0) |
| Talca |
Copa Libertadores 1970, First Round, Group 3 |
| 11.03.1970 | | América de Cali | – | Deportivo Cali | | 2:4 (1:3) |
| Santiago de Cali |
Copa Libertadores 1970, First Round, Group 3 |
| 01.03.1970 | | Deportivo Cali | – | América de Cali | | 4:2 (3:1) |
| Santiago de Cali |
Copa Libertadores 1970, First Round, Group 3 |
| 25.02.1970 | | Deportivo Cali | – | Rangers | | 3:2 (0:1) |
| Santiago de Cali |
Copa Libertadores 1970, First Round, Group 3 |
| 15.02.1970 | | Deportivo Cali | – | Universidad de Chile | | 2:0 |
| Santiago de Cali |
Copa Libertadores 1969, Second round, group 2 |
| 06.04.1969 | | Deportivo Cali | – | Santiago Wanderers | | 5:1 (3:1) |
| Santiago de Cali |
Copa Libertadores 1969, First Round, Group 1 |
| 16.03.1969 | | Deportivo Cali | – | Canarias |  | 2:0 (0:0) |
| Santiago de Cali |
Copa Libertadores 1969, First Round, Group 1 |
| 13.03.1969 | | Deportivo Cali | – | Deportivo Italia | | 3:0 (2:0) |
| Santiago de Cali |
Copa Libertadores 1969, First Round, Group 1 |
| 09.03.1969 | | Deportivo Cali | – | Unión Magdalena | | 3:1 (1:1) |
| Santiago de Cali |
Copa Libertadores 1968, First Round, Group 1 |
| 28.02.1968 | | Deportivo Cali | – | Los Millonarios | | 1:0 (0:0) |
| Santiago de Cali |
Copa Libertadores 1968, First Round, Group 1 |
| 08.02.1968 | | Deportivo Cali | – | Independiente Avellaneda | | 1:0 (0:0) |
| Santiago de Cali |
Superclásico
Copa Newton
Copa Lipton
Copa Rosa
Copa Félix Bogado
Copa Carlos Dittborn
Copa Ramón Castilla
Copa Rio Branco
Copa Rodrigues Alves
Taça Bernardo O'Higgins
Copa Artigas
Copa Paz del Chaco
Copa del Pacífico
