Europa League 2022/23, Round of 32 |
 | 16.02.2023 |  | Sevilla | – | PSV |  | 3:0 (1:0) |
| Sevilla |
Europa League 2022/23, Group A |
| 20.10.2022 |  | Arsenal | – | PSV | | 1:0 (0:0) |
| London |
Europa League 2021/22, Group B |
| 09.12.2021 | | Real Sociedad | – | PSV | | 3:0 (1:0) |
| San Sebastián |
Europa League 2021/22, Group B |
| 21.10.2021 | | PSV | – | Monaco |  | 1:2 (0:1) |
| Eindhoven |
Europa League 2020/21, Round of 32 |
| 18.02.2021 |  | Olympiakós Pireus | – | PSV | | 4:2 (3:2) * |
| Piraeus |
Europa League 2020/21, Group E |
| 05.11.2020 | | PAÓK | – | PSV | | 4:1 (0:1) |
| Thessaloniki |
Europa League 2020/21, Group E |
| 22.10.2020 | | PSV | – | Granada | | 1:2 (1:0) * |
| Eindhoven |
Europa League 2019/20, Group D |
| 28.11.2019 |  | Sporting | – | PSV | | 4:0 (3:0) |
| Lisboa |
Europa League 2019/20, Group D |
| 07.11.2019 |  | LASK | – | PSV | | 4:1 (0:1) |
| Linz |
Europa League 2017/18, Third qualifying round |
| 03.08.2017 |  | Osijek | – | PSV | | 1:0 (1:0) |
| Osijek |
Europa League 2017/18, Third qualifying round |
| 27.07.2017 | | PSV | – | Osijek | | 0:1 (0:0) |
| Eindhoven |
Europa League 2014/15, Round of 32 |
| 26.02.2015 |  | Zenit | – | PSV | | 3:0 (1:0) |
| Saint Petersburg |
Europa League 2014/15, Round of 32 |
| 19.02.2015 | | PSV | – | Zenit | | 0:1 (0:0) |
 | Eindhoven |
Europa League 2014/15, Group E |
| 11.12.2014 | | PSV | – | Dynamo Moscow | | 0:1 (0:0) |
| Eindhoven |
Europa League 2014/15, Group E |
| 02.10.2014 | | Dynamo Moscow | – | PSV | | 1:0 (0:0) |
| Khimki |
Europa League 2013/14, Group B |
| 12.12.2013 | | PSV | – | Chornomorets Odesa |  | 0:1 (0:0) |
| Eindhoven |
Europa League 2013/14, Group B |
| 28.11.2013 |  | Ludogorets | – | PSV | | 2:0 (1:0) |
| Sofia |
Europa League 2013/14, Group B |
| 19.09.2013 | | PSV | – | Ludogorets | | 0:2 (0:0) |
| Eindhoven |
Europa League 2012/13, Group F |
| 22.11.2012 | | PSV | – | Dnipro | | 1:2 (1:1) |
| Eindhoven |
Europa League 2012/13, Group F |
| 08.11.2012 |  | AIK | – | PSV | | 1:0 (1:0) |
| Solna |
Europa League 2012/13, Group F |
| 20.09.2012 | | Dnipro | – | PSV | | 2:0 (0:0) |
| Dnipropetrovsk |
Europa League 2011/12, Round of 16 |
| 08.03.2012 | | Valencia | – | PSV | | 4:2 (3:0) |
| Valencia |
Europa League 2010/11, Quarterfinals |
| 07.04.2011 | | Benfica | – | PSV | | 4:1 (2:0) |
| Lisboa |
Europa League 2010/11, Play-off Round |
| 19.08.2010 | | Sibir | – | PSV | | 1:0 (0:0) |
| Novosibirsk |
Europa League 2009/10, 1/16 finals |
| 18.02.2010 |  | Hamburger SV | – | PSV | | 1:0 (1:0) |
| Hamburg |
UEFA Cup 2007/08, Quarterfinal |
| 10.04.2008 | | PSV | – | Fiorentina |  | 0:2 (0:1) |
| Eindhoven |
UEFA Cup 2007/08, 1/8 finals |
| 12.03.2008 | | PSV | – | Tottenham Hotspur | | 0:1 aet
(0:0, 0:1),
pen. 6:5 |
| Eindhoven |
UEFA Cup 2003/04, Quarterfinal |
| 14.04.2004 | | Newcastle United | – | PSV | | 2:1 (1:0) |
| Newcastle upon Tyne |
UEFA Cup 2001/02, 1/16 finals |
| 22.11.2001 | | PAÓK | – | PSV | | 3:2 (2:1) |
| Thessaloniki |
UEFA Cup 2000/01, Quarterfinal |
| 15.03.2001 | | PSV | – | Kaiserslautern | | 0:1 (0:0) |
| Eindhoven |
UEFA Cup 2000/01, Quarterfinal |
| 08.03.2001 | | Kaiserslautern | – | PSV | | 1:0 (1:0) |
| Kaiserslautern |
UEFA Cup 2000/01, 1/8 finals |
| 22.02.2001 | | Parma | – | PSV | | 3:2 (0:2) |
| Parma |
UEFA Cup 1995/96, Quarterfinal |
| 19.03.1996 | | PSV | – | Barcelona | | 2:3 (1:2) |
| Eindhoven |
UEFA Cup 1994/95, 1/32 finals |
| 13.09.1994 | | Bayer 04 | – | PSV | | 5:4 (4:2) |
| Leverkusen |
UEFA Cup 1993/94, 1/32 finals |
| 14.09.1993 | | Karlsruher | – | PSV | | 2:1 (2:1) |
| Karlsruhe |
UEFA Cup 1985/86, 1/16 finals |
| 06.11.1985 |  | Dnepr | – | PSV | | 1:0 (0:0) |
| Krivoy Rog |
UEFA Cup 1984/85, 1/16 finals |
| 07.11.1984 | | Manchester United | – | PSV | | 1:0 aet
(0:0, 0:0) |
| Manchester |
UEFA Cup 1984/85, 1/32 finals |
| 19.09.1984 |  | Vorwärts | – | PSV | | 2:0 (1:0) |
| Frankfurt (Oder) |
UEFA Cup 1983/84, 1/16 finals |
| 02.11.1983 | | Nottingham Forest | – | PSV | | 1:0 (0:0) |
| Nottingham |
UEFA Cup 1983/84, 1/16 finals |
| 19.10.1983 | | PSV | – | Nottingham Forest | | 1:2 (0:0) |
| Eindhoven |
UEFA Cup 1982/83, 1/32 finals |
| 29.09.1982 | | PSV | – | Dundee United |  | 0:2 (0:2) |
| Eindhoven |
UEFA Cup 1981/82, 1/16 finals |
| 21.10.1981 | | Rapid Wien | – | PSV | | 1:0 (0:0) |
| Wien |
UEFA Cup 1981/82, 1/32 finals |
| 30.09.1981 |  | Næstved | – | PSV | | 2:1 (0:0) |
| Næstved |
UEFA Cup 1980/81, 1/16 finals |
| 05.11.1980 |  | Hamburger SV | – | PSV | | 2:1 (0:0) |
| Hamburg |
UEFA Cup 1980/81, 1/32 finals |
| 01.10.1980 | | Wolverhampton Wanderers | – | PSV | | 1:0 (0:0) |
| Wolverhampton |
UEFA Cup 1979/80, 1/16 finals |
| 07.11.1979 | | Saint-Étienne | – | PSV | | 6:0 (3:0) |
| Saint-Étienne |
UEFA Cup 1977/78, Semifinal |
| 12.04.1978 | | Barcelona | – | PSV | | 3:1 (2:0) |
| Barcelona |
UEFA Cup 1977/78, Quarterfinal |
| 01.03.1978 | | Magdeburg | – | PSV | | 1:0 (0:0) |
| Magdeburg |
UEFA Cup 1971/72, 1/8 finals |
| 08.12.1971 |  | Lierse | – | PSV | | 4:0 (1:0) |
| Lier |
UEFA Cup 1971/72, 1/16 finals |
| 20.10.1971 | | Real Madrid | – | PSV | | 3:1 (2:1) |
| Madrid |
