UEFA Champions League 2022/23, Group B |
 | 12.10.2022 |  | Bayer 04 | – | Porto |  | 0:3 (0:1) |
| Leverkusen |
UEFA Champions League 2022/23, Group B |
| 04.10.2022 | | Porto | – | Bayer 04 | | 2:0 (0:0) |
| Porto |
UEFA Champions League 2022/23, Group B |
| 07.09.2022 |  | Brugge | – | Bayer 04 | | 1:0 (1:0) |
| Brugge |
UEFA Champions League 2019/20, Group D |
| 11.12.2019 | | Bayer 04 | – | Juventus |  | 0:2 (0:0) |
| Leverkusen |
UEFA Champions League 2019/20, Group D |
| 22.10.2019 |  | Atlético Madrid | – | Bayer 04 | | 1:0 (0:0) |
| Madrid |
UEFA Champions League 2019/20, Group D |
| 01.10.2019 | | Juventus | – | Bayer 04 | | 3:0 (1:0) |
| Torino |
UEFA Champions League 2019/20, Group D |
| 18.09.2019 | | Bayer 04 | – | Lokomotiv Moscow |  | 1:2 (1:2) |
| Leverkusen |
UEFA Champions League 2016/17, Round of 16 |
| 21.02.2017 | | Bayer 04 | – | Atlético | | 2:4 (0:2) |
| Leverkusen |
UEFA Champions League 2015/16, Group E |
| 04.11.2015 | | Roma | – | Bayer 04 | | 3:2 (2:0) |
| Roma |
UEFA Champions League 2015/16, Group E |
| 29.09.2015 | | Barcelona | – | Bayer 04 | | 2:1 (0:1) |
| Barcelona |
UEFA Champions League 2015/16, Play-off Round |
| 18.08.2015 | | Lazio | – | Bayer 04 | | 1:0 (0:0) |
| Roma |
UEFA Champions League 2014/15, Round of 16 |
| 17.03.2015 | | Atlético Madrid | – | Bayer 04 | | 1:0 aet
(1:0, 1:0),
pen. 3:2 |
| Madrid |
UEFA Champions League 2014/15, Group C |
| 26.11.2014 | | Bayer 04 | – | Monaco |  | 0:1 (0:0) |
 | Leverkusen |
UEFA Champions League 2014/15, Group C |
| 16.09.2014 | | Monaco | – | Bayer 04 | | 1:0 (0:0) |
| Monte Carlo |
UEFA Champions League 2013/14, Round of 16 |
| 12.03.2014 | | Paris Saint-Germain | – | Bayer 04 | | 2:1 (1:1) |
| Paris |
UEFA Champions League 2013/14, Round of 16 |
| 18.02.2014 | | Bayer 04 | – | Paris Saint-Germain | | 0:4 (0:3) |
| Leverkusen |
UEFA Champions League 2013/14, Group A |
| 27.11.2013 | | Bayer 04 | – | Manchester United |  | 0:5 (0:2) |
| Leverkusen |
UEFA Champions League 2013/14, Group A |
| 17.09.2013 | | Manchester United | – | Bayer 04 | | 4:2 (1:0) |
| Manchester |
UEFA Champions League 2011/12, Round of 16 |
| 07.03.2012 | | Barcelona | – | Bayer 04 | | 7:1 (2:0) |
| Barcelona |
UEFA Champions League 2011/12, Round of 16 |
| 14.02.2012 | | Bayer 04 | – | Barcelona | | 1:3 (0:1) |
| Leverkusen |
UEFA Champions League 2011/12, Group E |
| 01.11.2011 | | Valencia | – | Bayer 04 | | 3:1 (1:1) |
| Valencia |
UEFA Champions League 2011/12, Group E |
| 13.09.2011 | | Chelsea | – | Bayer 04 | | 2:0 (0:0) |
| London |
UEFA Champions League 2004/05, 1/8 finals |
| 09.03.2005 | | Bayer 04 | – | Liverpool | | 1:3 (0:2) |
| Leverkusen |
UEFA Champions League 2004/05, 1/8 finals |
| 22.02.2005 | | Liverpool | – | Bayer 04 | | 3:1 (2:0) |
| Liverpool |
UEFA Champions League 2004/05, Group B |
| 28.09.2004 |  | Dynamo Kiev | – | Bayer 04 | | 4:2 (1:0) |
| Kiev |
UEFA Champions League 2004/05, Third qualifying round |
| 25.08.2004 |  | Baník | – | Bayer 04 | | 2:1 (1:0) |
| Ostrava |
UEFA Champions League 2002/03, Group stage 2, group A |
| 19.03.2003 | | Bayer 04 | – | Inter Milano | | 0:2 (0:1) |
| Leverkusen |
UEFA Champions League 2002/03, Group stage 2, group A |
| 11.03.2003 | | Barcelona | – | Bayer 04 | | 2:0 (1:0) |
| Barcelona |
UEFA Champions League 2002/03, Group stage 2, group A |
| 26.02.2003 | | Newcastle United | – | Bayer 04 | | 3:1 (3:0) |
| Newcastle upon Tyne |
UEFA Champions League 2002/03, Group stage 2, group A |
| 18.02.2003 | | Bayer 04 | – | Newcastle United | | 1:3 (1:3) |
| Leverkusen |
UEFA Champions League 2002/03, Group stage 2, group A |
| 10.12.2002 | | Inter Milano | – | Bayer 04 | | 3:2 (2:0) |
| Milano |
UEFA Champions League 2002/03, Group stage 2, group A |
| 27.11.2002 | | Bayer 04 | – | Barcelona | | 1:2 (1:0) |
| Leverkusen |
UEFA Champions League 2002/03, Group stage 1, group F |
| 13.11.2002 | | Manchester United | – | Bayer 04 | | 2:0 (1:0) |
| Manchester |
UEFA Champions League 2002/03, Group stage 1, group F |
| 24.09.2002 | | Bayer 04 | – | Manchester United | | 1:2 (0:2) |
| Leverkusen |
UEFA Champions League 2002/03, Group stage 1, group F |
| 18.09.2002 |  | Olympiakós Pireus | – | Bayer 04 | | 6:2 (3:1) |
| Piraeus |
UEFA Champions League 2001/02, Final |
| 15.05.2002 | | Real Madrid | – | Bayer 04 | | 2:1 (2:1) |
| Scotland, Glasgow |
UEFA Champions League 2001/02, Quarterfinal |
| 03.04.2002 | | Liverpool | – | Bayer 04 | | 1:0 (1:0) |
| Liverpool |
UEFA Champions League 2001/02, Group stage 2, group D |
| 27.02.2002 | | Arsenal | – | Bayer 04 | | 4:1 (2:0) |
| London |
UEFA Champions League 2001/02, Group stage 2, group D |
| 29.11.2001 | | Juventus | – | Bayer 04 | | 4:0 (3:0) |
| Torino |
UEFA Champions League 2001/02, Group stage 1, group F |
| 31.10.2001 | | Bayer 04 | – | Lyon | | 2:4 (1:2) |
| Leverkusen |
UEFA Champions League 2001/02, Group stage 1, group F |
| 17.10.2001 | | Barcelona | – | Bayer 04 | | 2:1 (2:1) |
| Barcelona |
UEFA Champions League 2000/01, Group stage 1, group A |
| 17.10.2000 | | Real Madrid | – | Bayer 04 | | 5:3 (2:1) |
| Madrid |
UEFA Champions League 2000/01, Group stage 1, group A |
| 27.09.2000 | | Bayer 04 | – | Real Madrid | | 2:3 (2:1) |
| Leverkusen |
UEFA Champions League 2000/01, Group stage 1, group A |
| 12.09.2000 | | Spartak Moscow | – | Bayer 04 | | 2:0 (0:0) |
| Moscow |
UEFA Champions League 1999/00, Group stage 1, group A |
| 19.10.1999 | | Dynamo Kiev | – | Bayer 04 | | 4:2 (2:1) |
| Kiev |
UEFA Champions League 1997/98, Quarterfinal |
| 18.03.1998 | | Real Madrid | – | Bayer 04 | | 3:0 (0:0) |
| Madrid |
UEFA Champions League 1997/98, Group F |
| 01.10.1997 | | Monaco | – | Bayer 04 | | 4:0 (1:0) |
| Monte Carlo |
UEFA Champions League 1997/98, Second qualifying round |
| 27.08.1997 |  | Dinamo Tbilisi | – | Bayer 04 | | 1:0 (1:0) |
| Tbilisi |
