Copa América 2021, Group A |
 | 21.06.2021 |  | Uruguay | – | Chile |  | 1:1 (0:1) * |
| Cuiabá |
Copa América 2021, Group A |
| 14.06.2021 |  | Argentina | – | Chile | | 1:1 (1:0) * |
| Rio de Janeiro |
Copa América 2019, Quarterfinal |
| 28.06.2019 |  | Colombia | – | Chile | | 0:0,
pen. 4:5 |
| São Paulo |
Copa América Centenario 2016 (commemorative), Final |
| 26.06.2016 | | Argentina | – | Chile | | 0:0 aet,
pen. 2:4 |
| East Rutherford |
Copa América 2015, Final |
| 04.07.2015 | | Chile | – | Argentina | | 0:0 aet,
pen. 4:1 |
| Santiago |
Copa América 2015, Group A |
| 15.06.2015 | | Chile | – | Mexico |  | 3:3 (2:2) |
| Santiago |
Copa América 2011, Group C |
| 08.07.2011 | | Uruguay | – | Chile | | 1:1 (0:0) |
| Mendoza |
Copa América 2007, Group B |
| 04.07.2007 | | Mexico | – | Chile | | 0:0 |
| Puerto la Cruz |
Copa América 2004, Group C |
| 11.07.2004 |  | Paraguay | – | Chile | | 1:1 (0:0) |
| Arequipa |
Copa América 1999, Semifinal |
| 13.07.1999 | | Uruguay | – | Chile | | 1:1 (1:0),
pen. 5:3 |
| Asunción |
Copa América 1995, Group C |
| 14.07.1995 | | Chile | – | Bolivia |  | 2:2 (0:0) |
| Paysandú |
Copa América 1991, Final Round |
| 19.07.1991 | | Chile | – | Argentina | | 0:0 |
| Santiago |
Copa América 1991, Final Round |
| 17.07.1991 | | Chile | – | Colombia | | 1:1 (0:1) |
| Santiago |
Copa América 1983, Group 1 |
| 21.09.1983 |  | Venezuela | – | Chile | | 0:0 |
| Caracas |
Copa América 1979, Final |
| 11.12.1979 | | Paraguay | – | Chile | | 0:0 |
| Buenos Aires |
Copa América 1979, Semifinal |
| 24.10.1979 | | Chile | – | Peru |  | 0:0 |
| Santiago |
Copa América 1979, Group 1 |
| 08.08.1979 | | Venezuela | – | Chile | | 1:1 (0:0) |
| San Cristóbal |
Copa América 1975, Group 2 |
| 17.07.1975 | | Chile | – | Peru | | 1:1 (1:0) |
| Santiago |
South American Championship 1967, Final tournament, Final Round |
| 01.02.1967 | | Bolivia | – | Chile | | 0:0 |
| Montevideo |
South American Championship 1967, Final tournament, Final Round |
| 26.01.1967 | | Uruguay | – | Chile | | 2:2 (1:2) |
| Montevideo |
South American Championship 1967, Qualifying tournament, Qualifying round |
| 11.12.1966 | | Colombia | – | Chile | | 0:0 |
| Bogotá |
South American Championship 1959, Final Round |
| 21.03.1959 | | Chile | – | Peru | | 1:1 (0:1) |
| Buenos Aires |
South American Championship 1957, Final Round |
| 24.03.1957 | | Chile | – | Ecuador |  | 2:2 (2:1) |
| Lima |
South American Championship 1955, Final Round |
| 13.03.1955 | | Chile | – | Uruguay | | 2:2 (1:2) |
| Santiago |
South American Championship 1953, Final Round |
| 28.03.1953 | | Chile | – | Bolivia | | 2:2 (1:1) |
| Lima |
South American Championship 1953, Final Round |
| 04.03.1953 | | Peru | – | Chile | | 0:0 |
| Lima |
South American Championship 1949, Final Round |
| 20.04.1949 | | Chile | – | Colombia | | 1:1 (1:0) |
| Rio de Janeiro |
South American Championship 1947, Final Round |
| 16.12.1947 | | Argentina | – | Chile | | 1:1 (1:1) |
| Guayaquil |
South American Championship 1945 (unofficial), Final Round |
| 11.02.1945 | | Chile | – | Argentina | | 1:1 (1:0) |
| Santiago |
South American Championship 1942, Final Round |
| 07.02.1942 | | Peru | – | Chile | | 0:0 |
| Montevideo |
South American Championship 1942, Final Round |
| 31.01.1942 | | Argentina | – | Chile | | 0:0 |
| Montevideo |
South American Championship 1937, Final Round |
| 21.01.1937 | | Peru | – | Chile | | 2:2 (2:1) |
| Buenos Aires |
South American Championship 1926, Final Round |
| 31.10.1926 | | Chile | – | Argentina | | 1:1 (1:1) |
| Santiago |
South American Championship 1922, Final Round |
| 17.09.1922 |  | Brazil | – | Chile | | 1:1 (1:1) |
| Rio de Janeiro |
South American Championship 1920, Final Round |
| 17.09.1920 | | Chile | – | Argentina | | 1:1 (1:1) |
| Viña del Mar |
South American Championship 1916 (unofficial), Final Round |
| 08.07.1916 | | Chile | – | Brazil | | 1:1 (0:1) |
| Buenos Aires Cancha de Gimnasia y Esgrima |
