African Cup of Nations 2023, Qualifying tournament, Group A |
 | 10.09.2023 |  | Nigeria | – | São Tomé and Príncipe |  | 6:0 (2:0) |
| Uyo |
African Cup of Nations 2023, Qualifying tournament, Group A |
| 14.06.2023 | | São Tomé and Príncipe | – | Guinea-Bissau |  | 0:1 (0:0) |
| Guinea-Bissau, Bissau |
African Cup of Nations 2023, Qualifying tournament, Group A |
| 26.03.2023 | | São Tomé and Príncipe | – | Sierra Leone |  | 0:2 (0:2) |
| Morocco, Agadir |
African Cup of Nations 2023, Qualifying tournament, Group A |
| 13.06.2022 | | São Tomé and Príncipe | – | Nigeria | | 0:10 (0:3) |
| Morocco, Agadir |
African Cup of Nations 2023, Qualifying tournament, Group A |
| 09.06.2022 | | Guinea-Bissau | – | São Tomé and Príncipe | | 5:1 (1:1) |
| Morocco, Agadir |
African Cup of Nations 2021, Qualifying tournament, Group C |
| 28.03.2021 |  | Ghana | – | São Tomé and Príncipe | | 3:1 (2:0) |
| Cape Coast |
African Cup of Nations 2021, Qualifying tournament, Group C |
| 24.03.2021 | | São Tomé and Príncipe | – | Sudan |  | 0:2 (0:1) |
| São Tomé |
African Cup of Nations 2021, Qualifying tournament, Group C |
| 16.11.2020 | | São Tomé and Príncipe | – | South Africa |  | 2:4 (1:1) * |
| São Tomé |
African Cup of Nations 2021, Qualifying tournament, Group C |
| 13.11.2020 | | South Africa | – | São Tomé and Príncipe | | 2:0 (0:0) * |
| Johannesburg |
African Cup of Nations 2021, Qualifying tournament, Group C |
| 18.11.2019 | | São Tomé and Príncipe | – | Ghana | | 0:1 (0:0) |
| São Tomé |
African Cup of Nations 2021, Qualifying tournament, Group C |
| 13.11.2019 | | Sudan | – | São Tomé and Príncipe | | 4:0 (2:0) |
| Omdurman |
African Cup of Nations 2019, Qualifying tournament, Preliminary Round |
| 26.03.2017 |  | Madagascar | – | São Tomé and Príncipe | | 3:2 (2:1) |
| Antananarivo |
African Cup of Nations 2019, Qualifying tournament, Preliminary Round |
| 22.03.2017 | | São Tomé and Príncipe | – | Madagascar | | 0:1 (0:0) |
| São Tomé |
African Cup of Nations 2017, Qualifying tournament, Group F |
| 04.09.2016 |  | Morocco | – | São Tomé and Príncipe | | 2:0 (0:0) |
| Rabat |
African Cup of Nations 2017, Qualifying tournament, Group F |
| 04.06.2016 | | São Tomé and Príncipe | – | Cape Verde |  | 1:2 (0:0) |
| São Tomé |
African Cup of Nations 2017, Qualifying tournament, Group F |
| 28.03.2016 |  | Libya | – | São Tomé and Príncipe | | 4:0 (0:0) |
| Algeria, Blida |
African Cup of Nations 2017, Qualifying tournament, Group F |
| 05.09.2015 | | São Tomé and Príncipe | – | Morocco | | 0:3 (0:3) |
| São Tomé |
African Cup of Nations 2017, Qualifying tournament, Group F |
| 13.06.2015 | | Cape Verde | – | São Tomé and Príncipe | | 7:1 (4:0) |
| Praia |
African Cup of Nations 2015, Qualifying tournament, First Round |
| 01.06.2014 |  | Benin | – | São Tomé and Príncipe | | 2:0 (1:0) |
| Cotonou |
African Cup of Nations 2015, Qualifying tournament, First Round |
| 17.05.2014 | | São Tomé and Príncipe | – | Benin | | 0:2 (0:0) |
| São Tomé |
African Cup of Nations 2013, Qualifying tournament, First Round |
| 16.06.2012 | | Sierra Leone | – | São Tomé and Príncipe | | 4:2 (4:1) |
| Freetown |
African Cup of Nations 2002, Qualifying tournament, Preliminary Round |
| 15.07.2000 |  | Gabon | – | São Tomé and Príncipe | | 4:1 (2:0) |
| Libreville |
African Cup of Nations 2000, Qualifying tournament, Preliminary Round |
| 18.08.1998 |  | Togo | – | São Tomé and Príncipe | | 2:0 (1:0) |
| Lomé |
African Cup of Nations 2000, Qualifying tournament, Preliminary Round |
| 02.08.1998 | | São Tomé and Príncipe | – | Togo | | 0:4 (0:2) |
| Gabon, Libreville |
